NiO-YSZ-石墨水系浆料的研制及其在注浆成型制备固体氧化物燃料电池中的应用

引用本文: 刘丹丹, 谢永敏, 刘江, 王金霞. NiO-YSZ-石墨水系浆料的研制及其在注浆成型制备固体氧化物燃料电池中的应用[J]. 物理化学学报, 2014, 30(2): 331-337. doi: 10.3866/PKU.WHXB201312241 shu

Citation: LIU Dan-Dan, XIE Yong-Min, LIU Jiang, WANG Jin-Xia. Preparation of NiO-YSZ-Graphite Aqueous Slurry and Its Application in Fabricating Solid Oxide Fuel Cells by Slip-Casting[J]. Acta Physico-Chimica Sinica, 2014, 30(2): 331-337. doi: 10.3866/PKU.WHXB201312241 shu

NiO-YSZ-石墨水系浆料的研制及其在注浆成型制备固体氧化物燃料电池中的应用

基金项目:
国家自然科学基金(21276097) (21276097)

浙江省自然科学基金(Y1090035)资助项目 (Y1090035)

摘要:

Ni-YSZ(钇稳定氧化锆)金属陶瓷普遍被用作固体氧化物燃料电池(SOFC)的阳极材料，其氧化物浆料的性质对湿法制备的SOFC的性能具有重要影响. 通过zeta 电位分析，研究了NiO-YSZ双分散相水系浆料的稳定性. 对六种分散剂作用于NiO、YSZ 表面的zeta 电位进行研究，发现采用的阴离子分散剂和两性分散剂使NiO 和YSZ在水中带有相反电荷而引起迅速絮凝；采用阳离子分散剂聚二烯二甲基氯化铵(PDAC)时，NiO 和YSZ因带有正电荷相互排斥而稳定分散于水中，在此基础上，加入作为SOFC阳极造孔剂的石墨，采用聚乙烯吡咯烷酮(PVP)作为石墨的分散剂，制备出了NiO-YSZ-石墨的稳定水系浆料. 采用此浆料通过注浆成型制得阳极支撑管，进而组装成SOFC单电池. 该单电池在800℃时最大功率密度达到509 mW·cm^-2；扫描电镜(SEM)分析表明电极与电解质间接触良好，阳极孔洞分布均匀.

关键词:

English

Preparation of NiO-YSZ-Graphite Aqueous Slurry and Its Application in Fabricating Solid Oxide Fuel Cells by Slip-Casting

1.
1 The Key Laboratory of Fuel Cell Technology of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China;
2 New Energy Research Institute, College of Environment and Energy, South China University of Technology, Guangzhou 510006, P. R. China;
3 Department of Electronics & Information Engineering, Ningbo University of Technology, Ningbo 315016, Zhejiang Province, P. R. China
Received Date: 22 October 2013
Available Online: 23 January 2014
Fund Project:
国家自然科学基金(21276097)

浙江省自然科学基金(Y1090035)资助项目

Abstract:

Cermet of Ni-YSZ (yttrium-stabilized zirconia) is commonly used as the anode material of solid oxide fuel cells (SOFCs) and the properties of the NiO-YSZ slurry has a significant effect on the performance of SOFCs prepared by wet processes. The stability of the NiO-YSZ slurry was investigated through zeta potential analysis. The effects of six dispersants on the surface zeta potentials of NiO and YSZ were examined. It was found that the zeta potential of NiO was opposite to that of YSZ when the anionic or amphoteric dispersant existed. When the cationic dispersant poly(diallyldimethylammonium chloride) (PDAC) was used, the zeta potentials for both NiO and YSZ were positive and they could be simultaneously suspended in water. By adding graphite, which is used as the pore former when fabricating the SOFC anode, into the NiO-YSZ suspension and using polyvinylpyrrolidone (PVP) as the dispersant of graphite, a stable NiO-YSZgraphite aqueous slurry was successfully prepared. The slurry was used to fabricate anode supports for SOFCs with the slip-casting technique. A typical single anode-supported SOFC showed a maximum power density of 509 mW·cm^-2 at 800℃. The microstructure of the SOFC with the anode support was examined by scanning electron microscope (SEM) analysis and it was found that the electrolyte and anode bonded well and the pores were homogenously distributed in the anode.

Key words:

1. [1]
  
  (1) Minh, N. Q.; Singhal, C.;Williams, M. ECS Transactions 2009,17 (1), 211.
  (1) Minh, N. Q.; Singhal, C.;Williams, M. ECS Transactions 2009,17 (1), 211.
2. [2]
  (2) Tang, Y. B.; Liu, J. Acta Physico-Chimica Sinica 2010, 26 (5),1191. [唐玉宝, 刘江. 物理化学学报, 2010, 26 (5), 1191.]doi: 10.3866/PKU.WHXB20100502(2) Tang, Y. B.; Liu, J. Acta Physico-Chimica Sinica 2010, 26 (5),1191. [唐玉宝, 刘江. 物理化学学报, 2010, 26 (5), 1191.]doi: 10.3866/PKU.WHXB20100502
3. [3]
  (3) Liu, M.; Dong, D.; Peng, R.; Gao, J.; Diwu, J.; Liu, X.; Meng,G. Journal of Power Sources 2008, 180 (1), 215. doi: 10.1016/j.jpowsour.2008.01.066(3) Liu, M.; Dong, D.; Peng, R.; Gao, J.; Diwu, J.; Liu, X.; Meng,G. Journal of Power Sources 2008, 180 (1), 215. doi: 10.1016/j.jpowsour.2008.01.066
4. [4]
  (4) Koide, H.; Someya, Y.; Yoshida, T.; Maruyama, T. Solid State Ionics 2000, 132 (3-4), 253.(4) Koide, H.; Someya, Y.; Yoshida, T.; Maruyama, T. Solid State Ionics 2000, 132 (3-4), 253.
5. [5]
  (5) Dong, J.; Cheng, Z.; Zha, S.; Liu, M. Journal of Power Sources2006, 156 (2), 461. doi: 10.1016/j.jpowsour.2005.06.016(5) Dong, J.; Cheng, Z.; Zha, S.; Liu, M. Journal of Power Sources2006, 156 (2), 461. doi: 10.1016/j.jpowsour.2005.06.016
6. [6]
  (6) He, T.; Lu, Z.; Huang, Y.; Guan, P.; Liu, J.; Su,W. Journal of Alloys and Compounds 2002, 337 (1-2), 231.(6) He, T.; Lu, Z.; Huang, Y.; Guan, P.; Liu, J.; Su,W. Journal of Alloys and Compounds 2002, 337 (1-2), 231.
7. [7]
  (7) Ding, J.; Liu, J.; Yuan,W.; Zhang, Y. Journal of the European Ceramic Society 2008, 28 (16), 3113. doi: 10.1016/j.jeurceramsoc.2008.05.033(7) Ding, J.; Liu, J.; Yuan,W.; Zhang, Y. Journal of the European Ceramic Society 2008, 28 (16), 3113. doi: 10.1016/j.jeurceramsoc.2008.05.033
8. [8]
  (8) Zhang, L.; He, H. Q.; Kwek,W. R.; Ma, J.; Tang, E. H.; Jiang,S. P. Journal of the American Ceramic Society 2009, 92 (2), 302.doi: 10.1111/jace.2009.92.issue-2(8) Zhang, L.; He, H. Q.; Kwek,W. R.; Ma, J.; Tang, E. H.; Jiang,S. P. Journal of the American Ceramic Society 2009, 92 (2), 302.doi: 10.1111/jace.2009.92.issue-2
9. [9]
  (9) Ramanathan, S.; Krishnakumar, K. P.; De, P. K.; Banerjee, S.Journal of Materials Science 2004, 39 (10), 3339. doi: 10.1023/B:JMSC.0000026934.88520.67(9) Ramanathan, S.; Krishnakumar, K. P.; De, P. K.; Banerjee, S.Journal of Materials Science 2004, 39 (10), 3339. doi: 10.1023/B:JMSC.0000026934.88520.67
10. [10]
  (10) Zhang, Y.; Liu, J.; Yin, J.; Yuan,W.; Sui, J. International Journal of Applied Ceramic Technology 2008, 5 (6), 568. doi: 10.1111/ijac.2008.5.issue-6(10) Zhang, Y.; Liu, J.; Yin, J.; Yuan,W.; Sui, J. International Journal of Applied Ceramic Technology 2008, 5 (6), 568. doi: 10.1111/ijac.2008.5.issue-6
11. [11]
  (11) Ding, J.; Liu, J. Journal of Power Sources 2009, 193 (2), 769.doi: 10.1016/j.jpowsour.2009.04.049(11) Ding, J.; Liu, J. Journal of Power Sources 2009, 193 (2), 769.doi: 10.1016/j.jpowsour.2009.04.049
12. [12]
  (12) Zürcher, S.; Graule, T. Journal of the European Ceramic Society2005, 25 (6), 863. doi: 10.1016/j.jeurceramsoc.2004.05.002(12) Zürcher, S.; Graule, T. Journal of the European Ceramic Society2005, 25 (6), 863. doi: 10.1016/j.jeurceramsoc.2004.05.002
13. [13]
  (13) Lewis, J. A. Journal of the American Ceramic Society 2000, 83 (10), 2341.(13) Lewis, J. A. Journal of the American Ceramic Society 2000, 83 (10), 2341.
14. [14]
  (14) Arevalo-Quintero, O.;Waldbillig, D.; Kesler, O. Surface and Coatings Technology 2011, 205 (21-22), 5218.(14) Arevalo-Quintero, O.;Waldbillig, D.; Kesler, O. Surface and Coatings Technology 2011, 205 (21-22), 5218.
15. [15]
  (15) Zhang, L.; Jiang, S. P.;Wang,W.; Zhang, Y. Journal of Power Sources 2007, 170 (1), 55. doi: 10.1016/j.jpowsour.2007.03.080(15) Zhang, L.; Jiang, S. P.;Wang,W.; Zhang, Y. Journal of Power Sources 2007, 170 (1), 55. doi: 10.1016/j.jpowsour.2007.03.080
16. [16]
  (16) Fonseca, C. G.; Basaglia, R. M. F.; Brant, M. C.; Matencio, T.;Domingues, R. Z. Powder Technology 2009, 192 (3), 352. doi: 10.1016/j.powtec.2009.01.022(16) Fonseca, C. G.; Basaglia, R. M. F.; Brant, M. C.; Matencio, T.;Domingues, R. Z. Powder Technology 2009, 192 (3), 352. doi: 10.1016/j.powtec.2009.01.022
17. [17]
  (17) Ramanathan, S.; Kakade, M. B. International Journal of Hydrogen Energy 2011, 36 (22), 14956. doi: 10.1016/j.ijhydene.2011.06.112(17) Ramanathan, S.; Kakade, M. B. International Journal of Hydrogen Energy 2011, 36 (22), 14956. doi: 10.1016/j.ijhydene.2011.06.112
18. [18]
  (18) Ding, J.; Liu, J. Solid State Ionics 2008, 179 (21-26), 1246.(18) Ding, J.; Liu, J. Solid State Ionics 2008, 179 (21-26), 1246.
19. [19]
  (19) Zhu, H.; Zhang, C.; Tang, Y.;Wang, J.; Ren, B.; Yin, Y. Carbon2007, 45, 203. doi: 10.1016/j.carbon.2006.10.007(19) Zhu, H.; Zhang, C.; Tang, Y.;Wang, J.; Ren, B.; Yin, Y. Carbon2007, 45, 203. doi: 10.1016/j.carbon.2006.10.007
20. [20]
  (20) Moon, H.; Kim, S. D.; Park, E.W.; Hyun, S. H.; Kim, H. S.International Journal of Hydrogen Energy 2008, 33 (11),2826. doi: 10.1016/j.ijhydene.2008.03.024(20) Moon, H.; Kim, S. D.; Park, E.W.; Hyun, S. H.; Kim, H. S.International Journal of Hydrogen Energy 2008, 33 (11),2826. doi: 10.1016/j.ijhydene.2008.03.024
21. [21]
  (21) Bai, Y.; Liu, J.; Gao, H.; Jin, C. Journal of Alloys and Compounds 2009, 480 (2), 554. doi: 10.1016/j.jallcom.2009.01.089(21) Bai, Y.; Liu, J.; Gao, H.; Jin, C. Journal of Alloys and Compounds 2009, 480 (2), 554. doi: 10.1016/j.jallcom.2009.01.089
22. [22]
  (22) Jin, C.; Liu, J.; Li, L.; Bai, Y. Journal of Membrane Science2009, 341 (1-2), 233.(22) Jin, C.; Liu, J.; Li, L.; Bai, Y. Journal of Membrane Science2009, 341 (1-2), 233.
23. [23]
  (23) Bai, Y.; Liu, J.;Wang, C. International Journal of Hydrogen Energy 2009, 34 (17), 7311. doi: 10.1016/j.ijhydene.2009.07.004(23) Bai, Y.; Liu, J.;Wang, C. International Journal of Hydrogen Energy 2009, 34 (17), 7311. doi: 10.1016/j.ijhydene.2009.07.004
24. [24]
  (24) Greenwood, R. Advances in Colloid and Interface Science 2003,106 (1-3), 55.(24) Greenwood, R. Advances in Colloid and Interface Science 2003,106 (1-3), 55.
25. [25]
  (25) Fu, Y. P.; Chen, S. H. Ceramics International 2009, 35 (2), 821.doi: 10.1016/j.ceramint.2008.02.018(25) Fu, Y. P.; Chen, S. H. Ceramics International 2009, 35 (2), 821.doi: 10.1016/j.ceramint.2008.02.018
26. [26]
  (26) Greenwood, R.; Kendall, K. Journal of the European Ceramic Society 2000, 20 (1), 77. doi: 10.1016/S0955-2219(99)00091-6(26) Greenwood, R.; Kendall, K. Journal of the European Ceramic Society 2000, 20 (1), 77. doi: 10.1016/S0955-2219(99)00091-6
27. [27]
  (27) Zhang, Y.; Gao, J.; Peng, D.; Guangyao, M.; Liu, X. Ceramics International 2004, 30 (6), 1049. doi: 10.1016/j.ceramint.2003.10.026(27) Zhang, Y.; Gao, J.; Peng, D.; Guangyao, M.; Liu, X. Ceramics International 2004, 30 (6), 1049. doi: 10.1016/j.ceramint.2003.10.026
28. [28]
  (28) Wang, Y. H.; Liu, X. Q.; Meng, G. Y. Ceramics International2007, 33 (6), 1025. doi: 10.1016/j.ceramint.2006.03.011(28) Wang, Y. H.; Liu, X. Q.; Meng, G. Y. Ceramics International2007, 33 (6), 1025. doi: 10.1016/j.ceramint.2006.03.011
29. [29]
  (29) Richardson, J.; Orte , J., Jr.; Coute, N.; Twigg, M. Catal Lett.1996, 41 (1-2), 17. doi: 10.1007/BF00811706
  (29) Richardson, J.; Orte , J., Jr.; Coute, N.; Twigg, M. Catal Lett.1996, 41 (1-2), 17. doi: 10.1007/BF00811706

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

NiO-YSZ-石墨水系浆料的研制及其在注浆成型制备固体氧化物燃料电池中的应用

English

Preparation of NiO-YSZ-Graphite Aqueous Slurry and Its Application in Fabricating Solid Oxide Fuel Cells by Slip-Casting

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

NiO-YSZ-石墨水系浆料的研制及其在注浆成型制备固体氧化物燃料电池中的应用

English

Preparation of NiO-YSZ-Graphite Aqueous Slurry and Its Application in Fabricating Solid Oxide Fuel Cells by Slip-Casting

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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