Nd<sup>3+</sup>/Yb<sup>3+</sup>离子共掺的氧化钛基上转换发光玻璃的热学和力学性能

引用本文: 于惠梅, 潘秀红, 张明辉, 刘岩, 余建定. Nd³⁺/Yb³⁺离子共掺的氧化钛基上转换发光玻璃的热学和力学性能[J]. 物理化学学报, 2014, 30(2): 227-231. doi: 10.3866/PKU.WHXB201312161 shu

Citation: YU Hui-Mei, PAN Xiu-Hong, ZHANG Ming-Hui, LIU Yan, YU Jian-Ding. Thermal and Mechanical Properties of Nd³⁺/Yb³⁺ Co-Doped Titanate Glass with Upconversion Emissions[J]. Acta Physico-Chimica Sinica, 2014, 30(2): 227-231. doi: 10.3866/PKU.WHXB201312161 shu

Nd³⁺/Yb³⁺离子共掺的氧化钛基上转换发光玻璃的热学和力学性能

基金项目:
国家自然科学基金(21005083)，中国科学院公派出国留学基金(201198)，中国科学院科研装备研制项目(YZ201142) (21005083)，中国科学院公派出国留学基金(201198)，中国科学院科研装备研制项目(YZ201142)

中国科学院上海硅酸盐研究所科技创新项目(Y17ZC1160G)资助 (Y17ZC1160G)

摘要:

利用气悬浮无容器技术制备出了Nd³⁺/Yb³⁺稀土离子共掺杂的TiO₂-La₂O₃-ZrO₂(TLZ)发光玻璃. 利用差热分析(DTA)技术研究了该类新型稀土掺杂TiO₂基上转换发光玻璃的热稳定性，主要包括玻璃化转变温度、析晶起始温度以及析晶峰值温度. 并采用两种热分析动力学计算方法得到TLZ玻璃的析晶活化能值和指前因子.本文还研究了TLZ 发光玻璃的力学性能，发现其维氏硬度大小为7.50 GPa，断裂韧性大于1.20 MPa·m^1/2. 此外，还对TLZ玻璃在808 nm激光激发下的上转换发光性能进行了研究，实验结果显示光谱中有三个强发射谱峰. 优异的上转换发光性能以及良好的热稳定性和机械性能表明，这类新材料在上转换器件的实际应用中具有很大的潜力.

关键词:

English

Thermal and Mechanical Properties of Nd³⁺/Yb³⁺ Co-Doped Titanate Glass with Upconversion Emissions

1.
1 Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, P. R. China;
2 Energy Institute, Pennsylvania State University, Pennsylvania 16802, USA
Received Date: 13 September 2013
Available Online: 23 January 2014
Fund Project:
国家自然科学基金(21005083)，中国科学院公派出国留学基金(201198)，中国科学院科研装备研制项目(YZ201142)

中国科学院上海硅酸盐研究所科技创新项目(Y17ZC1160G)资助

Abstract:

In the present work, Nd³⁺/Yb³⁺ co-doped TiO₂-La₂O₃-ZrO₂ (TLZ) glasses which were previously prepared by the aerodynamic levitation method were characterized by thermal differential analysis (DTA) and micro-hardness tests. The DTA technique was used to study the thermal stability of the characteristic temperatures, the glass transition temperature (T_g), the crystallization onset temperature (T_c), and the crystallization peak temperature (T_p), of the rare earth doped titanate glasses. The thermal kinetic DTA-analysis of the Nd³⁺/Yb³⁺ co-doped TLZ glasses was studied at heating rates of 5, 10, 15, 20 K·min^-1. The activation energy (E_a) and the pre-exponential factor (A) were obtained by the Kissinger and Friedman methods. In addition, the Vickers hardness was higher than 7.50 GPa and fracture toughness was higher than 1.20 MPa· m^1/2 for all the investigated TLZ glasses by the micro- hardness test. Furthermore, the upconversion luminescence property was investigated at 808 nm laser excitation, and three intense upconversion emission bands were observed. The excellent upconversion fluorescence, od thermal stability, and high mechanical strength suggested that this class of materials has potential for practical application in frequency upconversion devices.

Key words:

1. [1]
  
  (1) Giri, N. K.; Singh, A. K.; Rai, S. B. J. Appl. Phys. 2007, 101,033102. doi: 10.1063/1.2432305
  (1) Giri, N. K.; Singh, A. K.; Rai, S. B. J. Appl. Phys. 2007, 101,033102. doi: 10.1063/1.2432305
2. [2]
  (2) Silva, D. M.; Kassab, L. R. P.; Luthi, S. R.; Araujo, C. B.; mes, A. S. L.; Bell, M. J. V. Appl. Phys. Lett. 2007, 90,081913. doi: 10.1063/1.2679798(2) Silva, D. M.; Kassab, L. R. P.; Luthi, S. R.; Araujo, C. B.; mes, A. S. L.; Bell, M. J. V. Appl. Phys. Lett. 2007, 90,081913. doi: 10.1063/1.2679798
3. [3]
  (3) Fernandez, J.; Balda, R.; Mendioroz, A.; Sanz, M.; Adam, J. L.J. Non-Cryst. Solids 2001, 287, 437. doi: 10.1016/S0022-3093(01)00597-X(3) Fernandez, J.; Balda, R.; Mendioroz, A.; Sanz, M.; Adam, J. L.J. Non-Cryst. Solids 2001, 287, 437. doi: 10.1016/S0022-3093(01)00597-X
4. [4]
  (4) Som, T.; Karmakar, B. J. Alloy. Compd. 2009, 476, 383. doi: 10.1016/j.jallcom.2008.09.006(4) Som, T.; Karmakar, B. J. Alloy. Compd. 2009, 476, 383. doi: 10.1016/j.jallcom.2008.09.006
5. [5]
  (5) Feng, L.; Lai, B.;Wang, J.; Du, G.; Su, Q. J. Lumin. 2010, 130,2418. doi: 10.1016/j.jlumin.2010.08.005(5) Feng, L.; Lai, B.;Wang, J.; Du, G.; Su, Q. J. Lumin. 2010, 130,2418. doi: 10.1016/j.jlumin.2010.08.005
6. [6]
  (6) Karmakar, B. J. Solid State Chem. 2005, 178, 2663. doi: 10.1016/j.jssc.2005.06.007(6) Karmakar, B. J. Solid State Chem. 2005, 178, 2663. doi: 10.1016/j.jssc.2005.06.007
7. [7]
  (7) Porto, S. P. S.; Fleury, P. A.; Damen, T. C. Phys. Rev. 1967, 154,522. doi: 10.1103/PhysRev.154.522(7) Porto, S. P. S.; Fleury, P. A.; Damen, T. C. Phys. Rev. 1967, 154,522. doi: 10.1103/PhysRev.154.522
8. [8]
  (8) Mazza, T.; Barborini, E.; Piseri, P.; Milani, P.; Cattaneo, D.;Bassi, A. L.; Bottani, C. E.; Ducati, C. Phys. Rev. B 2007, 75,045416. doi: 10.1103/PhysRevB.75.045416(8) Mazza, T.; Barborini, E.; Piseri, P.; Milani, P.; Cattaneo, D.;Bassi, A. L.; Bottani, C. E.; Ducati, C. Phys. Rev. B 2007, 75,045416. doi: 10.1103/PhysRevB.75.045416
9. [9]
  (9) Pan, X. H.; Yu, J.; Liu, Y.; Zhang, M. H. J. Mater. Res. 2011, 26,2907. doi: 10.1557/jmr.2011.365(9) Pan, X. H.; Yu, J.; Liu, Y.; Zhang, M. H. J. Mater. Res. 2011, 26,2907. doi: 10.1557/jmr.2011.365
10. [10]
  (10) Plsko, A.; Liska, M.; Pagacova, J. J. Therm. Anal. Calorim.2012, 108, 505. doi: 10.1007/s10973-011-1967-x(10) Plsko, A.; Liska, M.; Pagacova, J. J. Therm. Anal. Calorim.2012, 108, 505. doi: 10.1007/s10973-011-1967-x
11. [11]
  (11) Jaqueline, L. M.; Antonio, R. S.; Aurelio, H. R.; Beatriz, Z.;Carlos, G. Y.; Roberto, M. S. Thermochim. Acta 2011, 516,35. doi: 10.1016/j.tca.2011.01.008(11) Jaqueline, L. M.; Antonio, R. S.; Aurelio, H. R.; Beatriz, Z.;Carlos, G. Y.; Roberto, M. S. Thermochim. Acta 2011, 516,35. doi: 10.1016/j.tca.2011.01.008
12. [12]
  (12) Yu, H. M.; Qi, L. J.; Zhang, Q. H.; Jiang, D. Y.; Lu, C. L.J. Therm. Anal. Calorim. 2011, 106, 47. doi: 10.1007/s10973-010-1280-0(12) Yu, H. M.; Qi, L. J.; Zhang, Q. H.; Jiang, D. Y.; Lu, C. L.J. Therm. Anal. Calorim. 2011, 106, 47. doi: 10.1007/s10973-010-1280-0
13. [13]
  (13) Zhang, K.; Liu, Q.; Su, X. B.; Zhong, H. M.; Shi, Y.; Pan, Y. B.Acta Phys. -Chim. Sin. 2011, 27 (8), 2001. [张孔, 刘茜,苏晓彬, 钟红梅, 石云, 潘裕柏. 物理化学学报, 2011, 27 (8),2001.] doi: 10.3866/PKU.WHXB20110732(13) Zhang, K.; Liu, Q.; Su, X. B.; Zhong, H. M.; Shi, Y.; Pan, Y. B.Acta Phys. -Chim. Sin. 2011, 27 (8), 2001. [张孔, 刘茜,苏晓彬, 钟红梅, 石云, 潘裕柏. 物理化学学报, 2011, 27 (8),2001.] doi: 10.3866/PKU.WHXB20110732
14. [14]
  (14) Yu, D.W.; Zhu, M. Q.; Utigard, T. A.; Barati, M. Thermochim. Acta 2014, 575, 1. doi: 10.1016/j.tca.2013.10.015(14) Yu, D.W.; Zhu, M. Q.; Utigard, T. A.; Barati, M. Thermochim. Acta 2014, 575, 1. doi: 10.1016/j.tca.2013.10.015
15. [15]
  (15) Abdel-Rehim, A. M. Thermochim. Acta 2012, 538, 29. doi: 10.1016/j.tca.2012.03.006(15) Abdel-Rehim, A. M. Thermochim. Acta 2012, 538, 29. doi: 10.1016/j.tca.2012.03.006
16. [16]
  (16) Pan, X. H.; Yu, J.; Liu, Y.; Yoda, S.; Yu, H. M.; Zhang, M. H.;Ai, F.; Jin, F.; Jin,W. Q. J. Alloy. Compd. 2011, 509, 7504. doi: 10.1016/j.jallcom.2011.04.104(16) Pan, X. H.; Yu, J.; Liu, Y.; Yoda, S.; Yu, H. M.; Zhang, M. H.;Ai, F.; Jin, F.; Jin,W. Q. J. Alloy. Compd. 2011, 509, 7504. doi: 10.1016/j.jallcom.2011.04.104
17. [17]
  (17) Babu, P.; Seo, H. J.; Kesavulu, C. R.; Jang, K. H.; Jayasankar,C. K. J. Lumin. 2009, 129, 444. doi: 10.1016/j.jlumin.2008.11.014(17) Babu, P.; Seo, H. J.; Kesavulu, C. R.; Jang, K. H.; Jayasankar,C. K. J. Lumin. 2009, 129, 444. doi: 10.1016/j.jlumin.2008.11.014
18. [18]
  (18) Koepke, C.; Piatkowski, D.;Wisniewski, K.; Naftaly, M.J. Non-Cryst. Solids 2010, 356, 435. doi: 10.1016/j.jnoncrysol.2009.12.012(18) Koepke, C.; Piatkowski, D.;Wisniewski, K.; Naftaly, M.J. Non-Cryst. Solids 2010, 356, 435. doi: 10.1016/j.jnoncrysol.2009.12.012
19. [19]
  (19) Abdel-Hameed, S. A. M.; El-kheshen, A. A. Ceram. Int. 2003,29, 265. doi: 10.1016/S0272-8842(02)00114-1(19) Abdel-Hameed, S. A. M.; El-kheshen, A. A. Ceram. Int. 2003,29, 265. doi: 10.1016/S0272-8842(02)00114-1
20. [20]
  (20) Xu, T.; Zhang, X.; Dai, S.; Nie, Q.; Shen, X.; Zhang, X. Physica B 2007, 389, 242. doi: 10.1016/j.physb.2006.06.156(20) Xu, T.; Zhang, X.; Dai, S.; Nie, Q.; Shen, X.; Zhang, X. Physica B 2007, 389, 242. doi: 10.1016/j.physb.2006.06.156
21. [21]
  (21) Simon, S.; Simon, V. Mater. Lett. 2004, 58, 3778. doi: 10.1016/j.matlet.2004.07.042(21) Simon, S.; Simon, V. Mater. Lett. 2004, 58, 3778. doi: 10.1016/j.matlet.2004.07.042
22. [22]
  (22) Opfermann, J. J. Therm. Anal. Calorim. 2000, 60, 641. doi: 10.1023/A:1010167626551(22) Opfermann, J. J. Therm. Anal. Calorim. 2000, 60, 641. doi: 10.1023/A:1010167626551
23. [23]
  (23) Hu, R. Z.; Gao, S. L.; Zhao, F. Q.; Shi, Q. Z.; Zhang, T. L.;Zhang, J. J. Thermal Analysis Kinetics; Sciences Press: Beijing,2008; pp 79-80. [胡荣祖, 高胜利, 赵凤起, 史启祯, 张同来,张建军. 热分析动力学. 北京: 科学出版社, 2008: 79-80.](23) Hu, R. Z.; Gao, S. L.; Zhao, F. Q.; Shi, Q. Z.; Zhang, T. L.;Zhang, J. J. Thermal Analysis Kinetics; Sciences Press: Beijing,2008; pp 79-80. [胡荣祖, 高胜利, 赵凤起, 史启祯, 张同来,张建军. 热分析动力学. 北京: 科学出版社, 2008: 79-80.]
24. [24]
  (24) Lin, M. T.; Jiang, D. Y.; Li, L.; Lu, Z. L.; Lai, T. R.; Shi, J. L.Mater. Sci. Eng. A 2003, 351, 9. doi: 10.1016/S0921-5093(01)01772-5(24) Lin, M. T.; Jiang, D. Y.; Li, L.; Lu, Z. L.; Lai, T. R.; Shi, J. L.Mater. Sci. Eng. A 2003, 351, 9. doi: 10.1016/S0921-5093(01)01772-5
25. [25]
  (25) Delben, A.; Messaddeq, Y.; Caridade, M. D.; Aegerter, M. A.;Eiras, J. A. J. Non-Cryst. Solids 1993, 161, 165. doi: 10.1016/0022-3093(93)90691-P(25) Delben, A.; Messaddeq, Y.; Caridade, M. D.; Aegerter, M. A.;Eiras, J. A. J. Non-Cryst. Solids 1993, 161, 165. doi: 10.1016/0022-3093(93)90691-P
26. [26]
  (26) Sampaio, J. A.; Baesso, M. L.; Gama, S.; Coelho, A. A.; Eiras, J.A.; Santos, I. A. J. Non-Cryst. Solids 2002, 304, 293. doi: 10.1016/S0022-3093(02)01037-2(26) Sampaio, J. A.; Baesso, M. L.; Gama, S.; Coelho, A. A.; Eiras, J.A.; Santos, I. A. J. Non-Cryst. Solids 2002, 304, 293. doi: 10.1016/S0022-3093(02)01037-2
27. [27]
  (27) Evans, A. G.; Charles, E. A. J. Am. Ceram. Soc. 1976, 59, 371.doi: 10.1111/jace.1976.59.issue-7-8
  (27) Evans, A. G.; Charles, E. A. J. Am. Ceram. Soc. 1976, 59, 371.doi: 10.1111/jace.1976.59.issue-7-8

扫一扫看文章

计量

PDF下载量: 535
文章访问数: 851
HTML全文浏览量: 17

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Nd³⁺/Yb³⁺离子共掺的氧化钛基上转换发光玻璃的热学和力学性能

English

Thermal and Mechanical Properties of Nd³⁺/Yb³⁺ Co-Doped Titanate Glass with Upconversion Emissions

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Nd3+/Yb3+离子共掺的氧化钛基上转换发光玻璃的热学和力学性能

English

Thermal and Mechanical Properties of Nd3+/Yb3+ Co-Doped Titanate Glass with Upconversion Emissions

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

Nd³⁺/Yb³⁺离子共掺的氧化钛基上转换发光玻璃的热学和力学性能

Thermal and Mechanical Properties of Nd³⁺/Yb³⁺ Co-Doped Titanate Glass with Upconversion Emissions

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs