纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附

引用本文: 李硕琦, 刘璐, 田辉凤, 胡劲波. 纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附[J]. 物理化学学报, 2011, 27(11): 2671-2676. doi: 10.3866/PKU.WHXB20111135 shu

Citation: LI Shuo-Qi, LIU Lu, TIAN Hui-Feng, HU Jing-Bo. High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate[J]. Acta Physico-Chimica Sinica, 2011, 27(11): 2671-2676. doi: 10.3866/PKU.WHXB20111135 shu

纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附

基金项目:
国家自然科学基金(20211130505) (20211130505)

中央高校基本科研业务费专项资金资助

摘要: 本文研究了纳米银(AgNPs)在氨基注入氧化铟锡(ITO)薄膜表面的吸附. 通过氨基注入的方法得到了氨基功能化的ITO表面(NH₂/ITO), 并将纳米银直接吸附在NH₂/ITO上得到纳米银修饰NH₂/ITO基体(AgNPs/NH₂/ITO). 使用傅里叶红外光谱、X射线光电子能谱、原子力显微镜、扫描电镜、紫外可见光谱和电化学方法对AgNPs/NH₂/ITO制备过程进行了表征. 结果显示纳米银可在NH₂/ITO表面高密度地吸附, 并且纳米银有良好的电化学活性. 这种不借助于有机连接分子吸附纳米银的方法为制备纳米银修饰材料提供了新的选择.

关键词:

离子注入
/ 组装
/ 纳米银
/ 氧化铟锡

English

High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate

1.
1. Key Laboratory of Beam Technology and Material Modification of Ministry of Education, Beijing Normal University, Beijing 100875, P. R. China;
2. College of Chemistry, Beijing Normal University, Beijing 100875, P. R. China;
3. College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China
Received Date: 01 August 2011
Available Online: 27 October 2011
Fund Project:
国家自然科学基金(20211130505)

中央高校基本科研业务费专项资金资助

Abstract: An effective approach to attach silver nanoparticles (AgNPs) directly onto an indium tin oxide (ITO) surface with high density was reported. An NH₂⁺ ion implanted ITO (NH₂/ITO) film was prepared and the AgNPs were adsorbed onto the surface of the obtained NH₂/ITO film resulting in an AgNPs-attached NH₂/ITO (AgNPs/NH₂/ITO) substrate. Characterization of stepwise changes in the ITO, NH₂/ITO, and AgNPs/NH₂/ITO surfaces were carried out using Fourier transform infrared (FT-IR) spectrometry, X-ray photoelectron spectroscopy (XPS), atomic force microscopy (AFM), scanning electron microscopy (SEM), ultravioletvisible (UV-Vis) spectroscopy, and electrochemical methods. Cyclic voltammtric voltammetry results indicate that the immobilized AgNPs on the NH₂/ITO electrode gave excellent electrochemical properties, implying facile electrochemical communication between the AgNPs and the ITO substrate through theby implanted amino groups. Thus, the AgNPs/NH₂/ITO surfaces are promising as new functional interfaces because AgNPs can be attached to surfaces without the use of organic binding molecules.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附

English

High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

纳米银粒子在氨基注入氧化铟锡玻璃基体表面的高密度吸附

English

High Density Attachment of Silver Nanoparticles onto an NH2+ Ion Implanted Indium Tin Oxide Glass Substrate

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

High Density Attachment of Silver Nanoparticles onto an NH₂⁺ Ion Implanted Indium Tin Oxide Glass Substrate

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs