引用本文:
于剑锋, 秦笃捷, 吴通好, 王国甲, 孙家鍾. 过度金属对缺位Keggin结构杂多化合物的修复[J]. 物理化学学报,
1998, 14(05): 435-438.
doi:
10.3866/PKU.WHXB19980510
Citation: Yu Jian-Feng, Qin Du-Jie, Wu Tong-Hao, Wang Guo-Jia, Sun Jia-Zhong. The Repair Effect of Transition-Metal lons on the Lacunary Heteropoly Complexes with Keggin Structure[J]. Acta Physico-Chimica Sinica, 1998, 14(05): 435-438. doi: 10.3866/PKU.WHXB19980510
Citation: Yu Jian-Feng, Qin Du-Jie, Wu Tong-Hao, Wang Guo-Jia, Sun Jia-Zhong. The Repair Effect of Transition-Metal lons on the Lacunary Heteropoly Complexes with Keggin Structure[J]. Acta Physico-Chimica Sinica, 1998, 14(05): 435-438. doi: 10.3866/PKU.WHXB19980510
过度金属对缺位Keggin结构杂多化合物的修复
摘要:
合成了第四周期过渡金属取代的Keggin结构钼磷、钨磷杂多化合物． 讨论了合成条件，运用P－O键的IR振动变化表征了过渡金属离子电子组态的变化对缺位配体的修复作用．
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关键词:
-
第四周期过渡金属
- / Keggin结构杂多化合物
- / 缺位单取代
- / P-O振动
English
The Repair Effect of Transition-Metal lons on the Lacunary Heteropoly Complexes with Keggin Structure
Abstract:
The 4th period transition-metal lacunary monosubstituted molybdophosphoric and tungstophosphoric complexes with Keggin structrue were synthesized. The synthesis conditions were discussed. The repair effect of the changing of the transition- metal ions electronic configuration on the substituted ligands was characterizated by the vibration of P-O.
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