引用本文:
李永红, 洪三国. SCRCR'CO重排反应的量子化学研究[J]. 物理化学学报,
1996, 12(02): 119-123.
doi:
10.3866/PKU.WHXB19960206
Citation: Li Yong-Hong, Hong San-Guo. Quantum Chemical Study on the Rearrangements of SCRCR'CO[J]. Acta Physico-Chimica Sinica, 1996, 12(02): 119-123. doi: 10.3866/PKU.WHXB19960206
Citation: Li Yong-Hong, Hong San-Guo. Quantum Chemical Study on the Rearrangements of SCRCR'CO[J]. Acta Physico-Chimica Sinica, 1996, 12(02): 119-123. doi: 10.3866/PKU.WHXB19960206
SCRCR'CO重排反应的量子化学研究
English
Quantum Chemical Study on the Rearrangements of SCRCR'CO
Abstract:
MINDO/3 MO method has been used to study on the rearrangements of SCRCR′CO. The results obtained show that the rearrangement reaction has lower activation energy when R is an election rich migrating group, and phenyl group can decrease the activation energy of this reaction.
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Key words:
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Rearrangement reaction
- / Transition state
- / Reaction pathway
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