Citation: Xu Jian-Ming, Wang Chang-Zhen, Sui Zhi-Tong. Investigation on the Thermodynamic Properties of Invar-type Alloys Containing Rare Rarth Metals[J]. Acta Physico-Chimica Sinica, 1994, 10(03): 276-280. doi: 10.3866/PKU.WHXB19940315
稀土Invar合金热力学性质研究
English
Investigation on the Thermodynamic Properties of Invar-type Alloys Containing Rare Rarth Metals
The invar-type alloys of YFe_(12-x)V_x (x=1.6, 2.0, 2.4, 2.8, 3.2) and SmFe_(12-x)V_x (x=2.4, 2.8) were prepared by melting elements in water cooled crucibles in a small are furnace with a magnetic stirring appratus. The activity and the relative partial molar Gibbs free energy of the Yttrium and Samariam in the alloys were determined by the emf method using the single crystal of CaF2 as a solid electrolyte at temperatures of 920-1020 K and 900-1000 K, respectively. The galvanic cell used can be expressed as
Mo|RE, REF_3|CaF_2|REF_3, REF_(12-x)V_x|Mo
The overall cell reaction is RE(S)=RE(alloys). The relative partial molar free energy of RE in alloy is equal to the free energy change of the cell reaction, ΔG_(RE)=ΔG=-3FE. If pure solid phase RE is chosen as the standard state, then ΔG_(RE)=RT Ina_(RE), a_(RE)=exp(-3FE/RT).
The experimental result shows that the activity of Y in alloys are larger than that of Sm in alloys, the SmFe_(12-x) alloys are therefore more stable.
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Key words:
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Rare earth
- / Invar-type alloys
- / Thermodynamic properties
- / Activity
- / Electromotive force method
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