引用本文:
王洪辉, 朱道本, 竺迺珏, 傅亨. 二[1,2-二硫代(3,5-二硫杂-4-硫酮)戊烯]铜和锌络合物的四丁基胺盐的晶体结构[J]. 物理化学学报,
1985, 1(04): 378-383.
doi:
10.3866/PKU.WHXB19850413
Citation: Wang Honghui, Zhu Daoben, Zhu Naijue, Fu Heng. CRYSTAL STRUCTURES OF TETRABUTYLAMMONIUM BIS(ISOTRITHIONEDITHIOLATO) COPPER (Ⅱ) AND ZINC (Ⅱ)[J]. Acta Physico-Chimica Sinica, 1985, 1(04): 378-383. doi: 10.3866/PKU.WHXB19850413
Citation: Wang Honghui, Zhu Daoben, Zhu Naijue, Fu Heng. CRYSTAL STRUCTURES OF TETRABUTYLAMMONIUM BIS(ISOTRITHIONEDITHIOLATO) COPPER (Ⅱ) AND ZINC (Ⅱ)[J]. Acta Physico-Chimica Sinica, 1985, 1(04): 378-383. doi: 10.3866/PKU.WHXB19850413
二[1,2-二硫代(3,5-二硫杂-4-硫酮)戊烯]铜和锌络合物的四丁基胺盐的晶体结构
English
CRYSTAL STRUCTURES OF TETRABUTYLAMMONIUM BIS(ISOTRITHIONEDITHIOLATO) COPPER (Ⅱ) AND ZINC (Ⅱ)
Abstract:
The crystal structures of the title compounds have been determined from threedimensional intensity measured on a R3m/E four circle diffractometer. The crystallographic data are listed in Table 1.
The structure of [N(C_4H_9)_4]_2[Cu(S_5C_3)_2] was solved by trial and error using isomophous [N(C_4H_9)_4]_2[Pd(S_5C_3)_2] crystal data. The structure of [N(C_4H_9)_4]_2[Zn(S_5C_3)_2] was solved by direct method using SHELXTL program system. The H atom coordinates were calculated geometrically. The refinement of coordinates and anisotropic thermal parameters was performed by “blocked cascade” least squares to R=0.044 for Cu(II) compound and R=0.057 for Zn(II) compound calculated on the basis of 2424 and 1219 independent reflections respectively. All the numerical calculations were carried out on a Eclipse/S_(140) computer with programs of R3m/E system.
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The structure of [N(C_4H_9)_4]_2[Cu(S_5C_3)_2] was solved by trial and error using isomophous [N(C_4H_9)_4]_2[Pd(S_5C_3)_2] crystal data. The structure of [N(C_4H_9)_4]_2[Zn(S_5C_3)_2] was solved by direct method using SHELXTL program system. The H atom coordinates were calculated geometrically. The refinement of coordinates and anisotropic thermal parameters was performed by “blocked cascade” least squares to R=0.044 for Cu(II) compound and R=0.057 for Zn(II) compound calculated on the basis of 2424 and 1219 independent reflections respectively. All the numerical calculations were carried out on a Eclipse/S_(140) computer with programs of R3m/E system.
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