单光子电离质谱法在线分析牙膏中的香精物质

引用本文: 谢园园, 花磊, 侯可勇, 陈平, 崔华鹏, 赵无垛, 陈文东, 李京华, 李海洋. 单光子电离质谱法在线分析牙膏中的香精物质[J]. 分析化学, 2012, 40(12): 1883-1889. doi: 10.3724/SP.J.1096.2012.20542 shu

Citation: XIE Yuan-Yuan, HUA Lei, HOU Ke-Yong, CHEN Ping, CUI Hua-Peng, ZHAO Wu-Duo, CHEN Wen-Dong, LI Jing-Hua, LI Hai-Yang. On-line Analysis of Flavor Compounds in Toothpastes by Single Photon Ionization Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, 2012, 40(12): 1883-1889. doi: 10.3724/SP.J.1096.2012.20542 shu

单光子电离质谱法在线分析牙膏中的香精物质

谢园园 ^1,2, ,
花磊 ^1, ,
侯可勇 ^1, ,
陈平 ^1,2, ,
崔华鹏 ^1,2, ,
赵无垛 ^1,2, ,
陈文东 ^1,2, ,
李京华 ^1, ,
李海洋 ^{1,
,}

通讯作者: 李海洋

基金项目:
本文系国家支撑项目

重大科学仪器设备(No.2011YQ05006904) (No.2011YQ05006904)

"863"计划(No.2011AA060602)以及国家自然科学基金(No.20907052)资助项目 (No.2011AA060602)以及国家自然科学基金(No.20907052)

摘要: 在无需样品前处理的条件下,建立了直接进样单光子电离飞行时间质谱在线分析牙膏样品中香精物质的方法。本方法采用石英毛细管直接将样品导入质谱仪电离区,优化了电离区气压条件,并利用香精标准品的特征质谱信号对牙膏样品中香精成分进行了快速、准确鉴定,单个样品分析仅需0.5 min。将本方法应用于模拟刷牙过程中挥发性香精的在线、原位监测,考察了水含量对牙膏香精挥发过程的影响。结果表明,直接进样单光子电离飞行时间质谱法能够实时监控刷牙过程中挥发香精的成分与浓度,可以应用于其他样品如食品、化妆品中香精成分的分析。

关键词:

English

On-line Analysis of Flavor Compounds in Toothpastes by Single Photon Ionization Mass Spectrometry

1.
¹ Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China;

Corresponding author: 李海洋

Received Date: 25 May 2012
Fund Project:
本文系国家支撑项目

重大科学仪器设备(No.2011YQ05006904)

"863"计划(No.2011AA060602)以及国家自然科学基金(No.20907052)资助项目

Abstract: A new method was developed for the on-line analysis of flavor compounds in toothpastes without any sample preparation by direct injection time-of-flight mass spectrometry with single photon ionization (SPI-TOFMS). The samples were directly taken into the ionization source by the quartz capillary tube and the pressure condition of the ionization source was optimized. Under the discrimination of characteristic mass spectra of flavor compounds, rapid and accurate identification of flavors in toothpastes was achieved. The analysis time for a single sample was only 0.5 min. This method was applied to on-line and in-situ monitoring of flavor compounds during tooth brushing process. The influence of water content on release of flavor compounds from toothpastes was studied. The results indicate that direct injection SPI-TOFMS can monitor the composition and concentration of flavor compounds in real time. The method could be suitable to analyze the flavors from various samples such as food and cosmetics.

Key words:

On-line analysis
/ Single photon ionization
/ On-line time-of-flight mass spectrometry
/ Toothpaste
/ Flavor compounds

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

单光子电离质谱法在线分析牙膏中的香精物质

通讯作者: 李海洋

English

On-line Analysis of Flavor Compounds in Toothpastes by Single Photon Ionization Mass Spectrometry

Corresponding author: 李海洋

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

单光子电离质谱法在线分析牙膏中的香精物质

通讯作者: 李海洋

English

On-line Analysis of Flavor Compounds in Toothpastes by Single Photon Ionization Mass Spectrometry

Corresponding author: 李海洋

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs