以金属有机框架材料HKUST-1为固定相的微型气相色谱柱

引用本文: 张娣, 张海燕, 陈泊鑫, 祝雨晨, 赵斌, 李磊, 郑丹, 冯飞. 以金属有机框架材料HKUST-1为固定相的微型气相色谱柱[J]. 分析化学, 2023, 51(3): 429-435. doi: 10.19756/j.issn.0253-3820.221492 shu

Citation: ZHANG Di, ZHANG Hai-Yan, CHEN Bo-Xin, ZHU Yu-Chen, ZHAO Bin, LI Lei, ZHENG Dan, FENG Fei. Micro Gas Chromatographic Column with HKUST-1 as A Stationary Phase[J]. Chinese Journal of Analytical Chemistry, 2023, 51(3): 429-435. doi: 10.19756/j.issn.0253-3820.221492 shu

以金属有机框架材料HKUST-1为固定相的微型气相色谱柱

张娣 ^1,2, ,
张海燕 ^1,2, ,
陈泊鑫 ^2, ,
祝雨晨 ^2, ,
赵斌 ^2, ,
李磊 ^2, ,
郑丹 ^{1,
,} ,
冯飞 ^{2,
,}

1.
上海应用技术大学化学与环境工程学院, 上海 201418;
2.
中国科学院上海微系统与信息技术研究所, 传感技术国家重点实验室, 上海 200050

通讯作者: 郑丹,E-mail:zhengdan@sit.edu.cn; 冯飞,E-mail:fengfei507@mail.sim.ac.cn

基金项目:
国家重点研发计划项目(Nos.2018YFA0208504,2021YFC2800301)、中国科学院战略性先导科技专项(A类)项目(No.XDA22020504)和上海科技创新行动计划医学创新研究专项项目(No.22Y11900600)资助。

摘要: 气相色谱柱微型化有利于气相色谱系统的小型化,然而对微型气相色谱柱而言,轻烃的分离是一个挑战。本研究基于微机电系统(MEMS)技术制备了微型气相色谱柱,在室温下合成了一种金属有机框架材料HKUST-1,采用动态涂敷法将HKUST-1涂敷到微型气相色谱柱中作为固定相。对以HKUST-1为固定相的微型气相色谱柱进行分离测试,结果表明,此微型气相色谱柱可以完全分离轻烃混合物(甲烷、乙烷、丙烷和正丁烷),其中难以分离的甲烷和乙烷的分离度达到9.2。

关键词:

English

Micro Gas Chromatographic Column with HKUST-1 as A Stationary Phase

ZHANG Di ^1,2, ,
ZHANG Hai-Yan ^1,2, ,
CHEN Bo-Xin ^2, ,
ZHU Yu-Chen ^2, ,
ZHAO Bin ^2, ,
LI Lei ^2, ,
ZHENG Dan ^{1,
,} ,
FENG Fei ^{2,
,}

1.
School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, China;
2.
State Key Laboratory of Transducer Technology, Shanghai Institute of Microsystem and Information Technology, Chinese Academy of Sciences, Shanghai 200050, China

Corresponding author: ZHENG Dan, ; FENG Fei,

Received Date: 04 October 2022
Revised Date: 24 November 2022
Fund Project:
Supported by the National Key R&D Program of China (Nos. 2018YFA0208504, 2021YFC2800301), the Strategic Priority Research Program of the Chinese Academy of Sciences (No. XDA22020504) and the Shanghai Science and Technology Innovation Action Plan, Medical Innovation Research Special Project (No. 22Y11900600).

Abstract: The miniaturization of gas chromatographic columns is beneficial to the miniaturization of gas chromatographic systems. The separation of light alkanes is a challenge for micro gas chromatographic columns (μGCC). Metal organic framework material is a new type of porous material that has been developed rapidly in the last two decades, and has attracted a lot of attention from researchers as stationary phases for gas chromatography. In this study, a μGCC was prepared based on MEMS technology, and a metal organic framework material HKUST-1 was synthesized at room temperature. HKUST-1 was coated into the μGCC as a stationary phase by dynamic coating method. The testing result of the μGCC with HKUST-1 stationary phase showed that the μGCC could completely separate light alkanes mixtures (methane, ethane, propane and n-butane), and the resolution of methane and ethane that were difficult to separate was 9.2.

Key words:

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

以金属有机框架材料HKUST-1为固定相的微型气相色谱柱

通讯作者: 郑丹,E-mail:zhengdan@sit.edu.cn; 冯飞,E-mail:fengfei507@mail.sim.ac.cn

English

Micro Gas Chromatographic Column with HKUST-1 as A Stationary Phase

Corresponding author: ZHENG Dan, ; FENG Fei,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

以金属有机框架材料HKUST-1为固定相的微型气相色谱柱

通讯作者: 郑丹,E-mail:zhengdan@sit.edu.cn; 冯飞,E-mail:fengfei507@mail.sim.ac.cn

English

Micro Gas Chromatographic Column with HKUST-1 as A Stationary Phase

Corresponding author: ZHENG Dan, ; FENG Fei,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs