基于短碳纳米管复合碘氧化铋-铋阴极光电化学传感平台测定毒死蜱

引用本文: 周建红, 刘彰, 令玉林, 曾伯平, 张衡, 邓克勤. 基于短碳纳米管复合碘氧化铋-铋阴极光电化学传感平台测定毒死蜱[J]. 分析化学, 2022, 50(2): 253-262. doi: 10.19756/j.issn.0253-3820.210758 shu

Citation: ZHOU Jian-Hong, LIU Zhang, LING Yu-Lin, ZENG Bo-Ping, ZHANG Heng, DENG Ke-Qin. Bismuth Oxyiodide-Bismuth Hybridized with Short Carbon Nanotubes as Cathode Photoelectrochemical Sensing Platform for Determination of Chlorpyrifos[J]. Chinese Journal of Analytical Chemistry, 2022, 50(2): 253-262. doi: 10.19756/j.issn.0253-3820.210758 shu

基于短碳纳米管复合碘氧化铋-铋阴极光电化学传感平台测定毒死蜱

周建红 ^{1,
,} ,
刘彰 ^2, ,
令玉林 ^3, ,
曾伯平 ^1, ,
张衡 ^2, ,
邓克勤 ^{2,
,}

1.
遵义师范学院生物与农业科技学院,遵义 563006;
2.
湖南科技大学化学化工学院,湘潭 411201;
3.
遵义师范学院资源与环境学院,遵义 563006

通讯作者: 周建红,E-mail:jianhongzhou@163.com; 邓克勤,E-mail:keqindeng@hnust.edu.cn

基金项目:
2021年“乡村振兴”专项项目（Nos.黔教合KY字[2012]017-18号、黔教合KY字[2012]017-10号）、遵义师范学院博士基金项目（Nos.遵师BS[2020]02号、遵师BS[2021]07号）和赤水河流域环境保护与山地农业发展人才基地开放基金项目资助

摘要: 通过简单的水热法将短碳纳米管(s-CNTs)与碘氧化铋-铋(BiOI-Bi)复合，制备了碘氧化铋-铋/短碳纳米管复合物(BiOI-Bi/s-CNTs)。采用扫描电子显微镜(SEM)进行表征，结果表明，BiOI-Bi/s-CNTs由负载纳米颗粒的s-CNTs和大量微球组成。瞬时光电流测量结果表明，BiOI-Bi/s-CNTs具有优良的光电化学(PEC)性能。以BiOI-Bi/s-CNTs为光电阴极，K₃[Fe(CN)₆]为光电子受体，构建了一种用于检测毒死蜱(CPF)的阴极PEC方法。由于CPF被螯合富集于阴极表面，可淬灭光电流信号，在4.0 pg/mL~10.0 ng/mL范围内，CPF的浓度与光电流变化值呈良好的线性关系，检出限(3σ)为1.89 pg/mL。本方法特异性好，灵敏度高，大白菜和卷心菜样品中CPF的加标回收率为90.0%~108.0%，表明可用于实际样品中CPF的灵敏检测。

关键词:

English

Bismuth Oxyiodide-Bismuth Hybridized with Short Carbon Nanotubes as Cathode Photoelectrochemical Sensing Platform for Determination of Chlorpyrifos

1.
College of Biological and Agricultural Science and Technology, Zunyi Normal University, Zunyi 563006, China;
2.
School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China;
3.
College of Resources and Environment, Zunyi Normal University, Zunyi 563006, China

Corresponding author: ZHOU Jian-Hong, ; DENG Ke-Qin,

Received Date: 22 September 2021
Revised Date: 17 December 2021
Fund Project:
Supported by the Rural Revitalization Project Launched in 2021 (Nos.Qian-Jiao-He KY-Zi [2012]017-18, [2012]017-10), the Doctor Introduction Fund Project of Zunyi Normal University (Nos.ZunshiBS[2020] 02, Zunshi BS[2021] 07) and the Talent Base for Environmental Protection and Mountain Agricultural in Chishui River Basin

Abstract: A bismuth oxyiodide-bismuth/short carbon nanotube (BiOI-Bi/s-CNTs) composite was prepared by hybridization of short carbon nanotubes (s-CNTs) with bismuth oxyiodide-bismuth (BiOI-Bi). The morphological analysis by scanning electron microscopy (SEM) showed that the prepared BiOI-Bi/s-CNTs consisted of s-CNTs loaded with nanoparticles and a large number of microspheres.Besides, the transient photocurrent displayed that the BiOI-Bi/s-CNTs had excellent photoelectrochemical performance. Thus, a novel cathodic photoelectrochemical method was developed for detection of chlorpyrifos (CPF) with BiOI-Bi/s-CNTs as photocathode and K₃[Fe(CN)₆] as photoelectron acceptor on the basis of that CPF chelated on the cathode surface and quenched the photocurrent signal. The CPF concentration in the range of 4.0 pg/mL-10.0 ng/mL was positively correlated with the quenched photocurrent, and the detection limit was estimated to be 1.89 pg/mL. The recoveries of CPF in real cabbage and Chinese cabbage were 90.0%-108.0%. This work provided a more specific and sensitive method for determination of CPF.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

基于短碳纳米管复合碘氧化铋-铋阴极光电化学传感平台测定毒死蜱

通讯作者: 周建红,E-mail:jianhongzhou@163.com; 邓克勤,E-mail:keqindeng@hnust.edu.cn

English

Bismuth Oxyiodide-Bismuth Hybridized with Short Carbon Nanotubes as Cathode Photoelectrochemical Sensing Platform for Determination of Chlorpyrifos

Corresponding author: ZHOU Jian-Hong, ; DENG Ke-Qin,

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

基于短碳纳米管复合碘氧化铋-铋阴极光电化学传感平台测定毒死蜱

通讯作者: 周建红,E-mail:jianhongzhou@163.com; 邓克勤,E-mail:keqindeng@hnust.edu.cn

English

Bismuth Oxyiodide-Bismuth Hybridized with Short Carbon Nanotubes as Cathode Photoelectrochemical Sensing Platform for Determination of Chlorpyrifos

Corresponding author: ZHOU Jian-Hong, ; DENG Ke-Qin,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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