聚多巴胺包覆的钙钛矿修饰电极用于电化学检测水中铜、汞和铅离子

引用本文: 韩玉洁, 代志鹏, 郑晓芳, 郭玉晶. 聚多巴胺包覆的钙钛矿修饰电极用于电化学检测水中铜、汞和铅离子[J]. 分析化学, 2022, 50(2): 206-216. doi: 10.19756/j.issn.0253-3820.210610 shu

Citation: HAN Yu-Jie, DAI Zhi-Peng, ZHENG Xiao-Fang, GUO Yu-Jing. Institute of Environmental Science, Shanxi University, Taiyuan 030006, China[J]. Chinese Journal of Analytical Chemistry, 2022, 50(2): 206-216. doi: 10.19756/j.issn.0253-3820.210610 shu

聚多巴胺包覆的钙钛矿修饰电极用于电化学检测水中铜、汞和铅离子

山西大学环境科学研究所,太原 030006

通讯作者: 郭玉晶,E-mail:guoyj@sxu.edu.cn

基金项目:
国家自然科学基金项目（No.21775095）资助

摘要: 通过水热法合成具有钙钛矿结构的LaCo_0.21Ni_1.59O₃，将聚多巴胺(PDA)包覆在LaCo_0.21Ni_1.59O₃表面，得到PDA@LaCo_0.21Ni_1.59O₃复合材料。利用钙钛矿优异的电催化性能和PDA丰富的胺基基团，将复合材料修饰在玻碳电极(GCE)表面，构建了一种新型电化学传感平台(PDA@LaCo_0.21Ni_1.59O₃/GCE)，用于重金属离子的检测。在优化条件下，LaCo_0.21Ni_1.59O₃/GCE检测Cu²⁺、Hg²⁺和Pb²⁺的线性范围分别为0.05~10.0 μmol/L、0.005~5.0 μmol/L和0.5~2.0 μmol/L，检出限分别为67.70、8.68和52.00 nmol/L。此传感平台可用于重金属离子Cu²⁺、Hg²⁺和Pb²⁺的同时检测，具有操作简单、灵敏度高、选择性好等特点，为重金属离子的检测提供了新方法。

关键词:

English

Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

Corresponding author: GUO Yu-Jing, guoyj@sxu.edu.cn

Received Date: 06 July 2021
Revised Date: 24 September 2021
Fund Project:
Supported by the National Natural Science Foundation of China (No.21775095)

Abstract: A core-shell structured polydopamine (PDA) functionalized LaCo_0.21Ni_1.59O₃ composite (PDA@LaCo_0.21Ni_1.59O₃) was synthesized, which combined the excellent electrocatalytic properties of LaCo_0.₂₁Ni_1.59O₃ and the abundant amino functional groups of PDA. On the basis of this, a novel electrochemical sensing platform for detection of heavy metal ions was constructed by modifying the composite on the glassy carbon electrode (PDA@LaCo_0.21Ni_1.59O₃/GCE). Under optimized conditions, the sensing platform showed wide linear range and low detection limit for Cu²⁺, Hg²⁺ and Pb²⁺ ions (The linear ranges were 0.05－10.0, 0.005－5.0 and 0.5－2.0 μmol/L, and the detection limits were 67.70, 8.68 and 52.0 nmol/L for Cu²⁺, Hg²⁺ and Pb²⁺ ions, respectively). The constructed sensing platform could be used for simultaneous detection of Cu²⁺, Hg²⁺ and Pb²⁺. This method provided a new strategy for the detection of heavy metals in water environment.

Key words:

1. [1]
  SUN Hua-Jie. Environ. Dev., 2019， 31(9): 57-58. 孙华杰. 环境与发展, 2019, 31(9): 57-58.
2. [2]
  RAJABI M, ABOLHOSSEINI M, HOSSEINI-BANDEGHARAEI A, HEMMATI M, GHASSAB N. Microchem. J., 2020, 159: 105450.RAJABI M, ABOLHOSSEINI M, HOSSEINI-BANDEGHARAEI A, HEMMATI M, GHASSAB N. Microchem. J., 2020, 159: 105450.
3. [3]
  DENG Q S, YANG C, ZHENG H T, LIU J X, MAO X F, HU S H, ZHU Z L. J. Anal. Atom. Spectrom., 2019, 34(9): 1786-1793.DENG Q S, YANG C, ZHENG H T, LIU J X, MAO X F, HU S H, ZHU Z L. J. Anal. Atom. Spectrom., 2019, 34(9): 1786-1793.
4. [4]
  MANOUSI N, DELIYANNI E, ZACHARIADIS G. Appl. Sci., 2020, 10(23): 8722.MANOUSI N, DELIYANNI E, ZACHARIADIS G. Appl. Sci., 2020, 10(23): 8722.
5. [5]
  QIN J X, SU Z, MAO Y H, LIU C C, QI B, FANG G Z, WANG S. Ecotoxicol. Environ. Saf., 2021, 208: 111729.QIN J X, SU Z, MAO Y H, LIU C C, QI B, FANG G Z, WANG S. Ecotoxicol. Environ. Saf., 2021, 208: 111729.
6. [6]
  CHEN B H, JIANG S J, SHAAYAM A C. Food Chem., 2020, 324: 126698.CHEN B H, JIANG S J, SHAAYAM A C. Food Chem., 2020, 324: 126698.
7. [7]
  WU Qian, BI Hong-Mei, HAN Xiao-Jun. Chin. J. Anal. Chem., 2021, 49(3): 330-340. 吴倩，毕洪梅，韩晓军. 分析化学， 2021, 49(3): 330-340.
8. [8]
  CHENG Z, BAI W S, JIN Y, ZHENG J B. Talanta, 2021, 323: 122405.CHENG Z, BAI W S, JIN Y, ZHENG J B. Talanta, 2021, 323: 122405.
9. [9]
  LU Y Y, LIANG X Q, XU J M. Sens. Actuators, B, 2018, 273: 1146-1155.LU Y Y, LIANG X Q, XU J M. Sens. Actuators, B, 2018, 273: 1146-1155.
10. [10]
  LU M X, DENG Y J, LUO Y, LV J P, LI T B, XU J. CHEN S W, WANG J Y. Anal. Chem., 2019, 91(1): 888-895.LU M X, DENG Y J, LUO Y, LV J P, LI T B, XU J. CHEN S W, WANG J Y. Anal. Chem., 2019, 91(1): 888-895.
11. [11]
  BANSOD B, KUMAR T, THAKUR R, RANA S, SINGH I. Biosens. Biolectron., 2017, 94: 443-455.BANSOD B, KUMAR T, THAKUR R, RANA S, SINGH I. Biosens. Biolectron., 2017, 94: 443-455.
12. [12]
  CLARA P R, JULIO B A, NURIA S, MANUEL D C J, CRISTINA A, JOAN D P, MIQUEL E. Sensors, 2017,17(6): 1458.CLARA P R, JULIO B A, NURIA S, MANUEL D C J, CRISTINA A, JOAN D P, MIQUEL E. Sensors, 2017,17(6): 1458.
13. [13]
  GUAN P, GUO P R, LIU N, ZHANG F, LEI Y Q. Analyst, 2018, 143(18): 4436-4441.GUAN P, GUO P R, LIU N, ZHANG F, LEI Y Q. Analyst, 2018, 143(18): 4436-4441.
14. [14]
  WANG L L, LEI T, REN Z X, JIANG X, YANG X J, BAI H P, WANG S X. J. Electronal. Chem., 2020, 864:114065.WANG L L, LEI T, REN Z X, JIANG X, YANG X J, BAI H P, WANG S X. J. Electronal. Chem., 2020, 864:114065.
15. [15]
  LI S S, CHENG X L, XU Q Q, ZHOU W Y, ZHANG Y X, YANG M. Electrochim. Acta, 2020, 360: 136991.LI S S, CHENG X L, XU Q Q, ZHOU W Y, ZHANG Y X, YANG M. Electrochim. Acta, 2020, 360: 136991.
16. [16]
  YAO L L, GAO S J, LIU S, BI Y L, WANG R R, QU H, WU Y E, MAO Y, ZHENG L. ACS Appl. Mater. Interfaces, 2020, 12(5): 6268-6275.YAO L L, GAO S J, LIU S, BI Y L, WANG R R, QU H, WU Y E, MAO Y, ZHENG L. ACS Appl. Mater. Interfaces, 2020, 12(5): 6268-6275.
17. [17]
  ZHANG Y Y, YU H, LIU T, LI W J, HAO X D, LU Q, LIANG X S, LIU F M, LIU F M, WANG C G,YANG C H, ZHU H Q, LU G Y. Anal. Chim. Acta, 2020, 1124: 166-175.ZHANG Y Y, YU H, LIU T, LI W J, HAO X D, LU Q, LIANG X S, LIU F M, LIU F M, WANG C G,YANG C H, ZHU H Q, LU G Y. Anal. Chim. Acta, 2020, 1124: 166-175.
18. [18]
  XIE F, YANG M, JIANG M, HUANG X J, LIU W Q, XIE P H. TrAC-Trends Anal. Chem., 2019, 119: 115624.XIE F, YANG M, JIANG M, HUANG X J, LIU W Q, XIE P H. TrAC-Trends Anal. Chem., 2019, 119: 115624.
19. [19]
  ZHOU J, WANG Q, LIU F L, XIONG S Q. Electrocatalysis, 2021, 12(4): 381-389.ZHOU J, WANG Q, LIU F L, XIONG S Q. Electrocatalysis, 2021, 12(4): 381-389.
20. [20]
  OULARBI L, TURMINE M, SALIH F E, EL RHAZI M. J. Environ. Chem. Eng., 2020, 8(3): 103774.OULARBI L, TURMINE M, SALIH F E, EL RHAZI M. J. Environ. Chem. Eng., 2020, 8(3): 103774.
21. [21]
  TAJIK S, BEITOLLAHI H, NEIAD F G, SHEIKHSHOAIE I, NUGRAHA A S, JANG H W, YAMAUCHI Y, SHOKOUHIMEHR M. J. Mater. Chem. A, 2021, 9(13): 8195-8220.TAJIK S, BEITOLLAHI H, NEIAD F G, SHEIKHSHOAIE I, NUGRAHA A S, JANG H W, YAMAUCHI Y, SHOKOUHIMEHR M. J. Mater. Chem. A, 2021, 9(13): 8195-8220.
22. [22]
  HUI X, SHARIFUZZAMAN M, SHARMA S, XUAN X, ZHANG S P, KO S G, YOON S H, PARK J Y. ACS Appl. Mater. Interfaces, 2020, 12(43): 48928-48937.HUI X, SHARIFUZZAMAN M, SHARMA S, XUAN X, ZHANG S P, KO S G, YOON S H, PARK J Y. ACS Appl. Mater. Interfaces, 2020, 12(43): 48928-48937.
23. [23]
  ZHU X L, LIU B C, HOU H J, HUANG Z Y, ZEINU K M, HUANG L, YUAN X Q, GUO D B, HU J P,YANG J K. Electrochim. Acta, 2017, 248: 46-57.ZHU X L, LIU B C, HOU H J, HUANG Z Y, ZEINU K M, HUANG L, YUAN X Q, GUO D B, HU J P,YANG J K. Electrochim. Acta, 2017, 248: 46-57.
24. [24]
  SUVINA V, KOKULNATHAN T, WANG T J, BALAKRISHNA R G. Microchim. Acta, 2020, 187(3): 189.SUVINA V, KOKULNATHAN T, WANG T J, BALAKRISHNA R G. Microchim. Acta, 2020, 187(3): 189.
25. [25]
  SUVINA V, KOKULNATHAN T, WANG T J, BALAKRISHNA R G. Ecotoxicol. Environ. Saf., 2020, 190: 110098.SUVINA V, KOKULNATHAN T, WANG T J, BALAKRISHNA R G. Ecotoxicol. Environ. Saf., 2020, 190: 110098.
26. [26]
  CHEN T W, RAMACHANDRAN R, CHEN S M, KAVITHA N, DINAKARAN K, KANNAN R, ANUSHYA G, BHUVANA N, JEYAPRAGASAM T, MARIYAPPAN V, RANI S D, CHITRA S. Catalysts, 2020, 10(8): 938.CHEN T W, RAMACHANDRAN R, CHEN S M, KAVITHA N, DINAKARAN K, KANNAN R, ANUSHYA G, BHUVANA N, JEYAPRAGASAM T, MARIYAPPAN V, RANI S D, CHITRA S. Catalysts, 2020, 10(8): 938.
27. [27]
  WANG H, QI J, YANG N L. Angew. Chem., Int. Ed., 2020, 59(44): 19691-19695.WANG H, QI J, YANG N L. Angew. Chem., Int. Ed., 2020, 59(44): 19691-19695.
28. [28]
  MA Yu-Rong, ZHOU Lu-Yue. Environ. Chem., 2018, 37(4): 817-823. 马玉荣，周陆跃. 环境化学, 2018, 37(4): 817-823.
29. [29]
  SONG W Q, POYRAZ A S, MENG Y T, REN Z, CHEN S Y, SUIB S L. Chem. Mater., 2014, 26: 4629-4639.SONG W Q, POYRAZ A S, MENG Y T, REN Z, CHEN S Y, SUIB S L. Chem. Mater., 2014, 26: 4629-4639.
30. [30]
  CHEN X, BAO X Y, XIAO Y, ZAHNG C S, TANG L N, YAO L, GUI G D, YANG Y. Appl. Surf. Sci., 2019, 466: 989-999.CHEN X, BAO X Y, XIAO Y, ZAHNG C S, TANG L N, YAO L, GUI G D, YANG Y. Appl. Surf. Sci., 2019, 466: 989-999.
31. [31]
  ZHU C Z, DAN W, LEUBNER S, OSCHATZ M, LIU W, HOLZSCHUH M, SIMON F, KASKEL S, EYCHMULLER A. Chem. Commun., 2015, 51: 7851-7854.ZHU C Z, DAN W, LEUBNER S, OSCHATZ M, LIU W, HOLZSCHUH M, SIMON F, KASKEL S, EYCHMULLER A. Chem. Commun., 2015, 51: 7851-7854.
32. [32]
  MA R G, ZHOU Y, CHEN Y F, LI P X, LIU Q, WANG J C. Angew. Chem., Int. Ed., 2015, 54(49): 14723-14727.MA R G, ZHOU Y, CHEN Y F, LI P X, LIU Q, WANG J C. Angew. Chem., Int. Ed., 2015, 54(49): 14723-14727.
33. [33]
  LIAO J J, ZHANG J P, WANG C Z. Anal. Chim. Acta, 2018, 1022: 37-44.LIAO J J, ZHANG J P, WANG C Z. Anal. Chim. Acta, 2018, 1022: 37-44.
34. [34]
  PEREZ-RAFOLS C, BASTOS-ARRIETA J, SERRANO N. Sensors, 2017, 14(6): 1458.PEREZ-RAFOLS C, BASTOS-ARRIETA J, SERRANO N. Sensors, 2017, 14(6): 1458.
35. [35]
  PRASONGPORN R, EAKKASIT P, ORAWON C. Electroanalysis, 2017, 29(4): 1022-1030.PRASONGPORN R, EAKKASIT P, ORAWON C. Electroanalysis, 2017, 29(4): 1022-1030.
36. [36]
  ZHOU S F, WANG J J, GAN L. J. Alloys Compd., 2017, 721: 492-500.ZHOU S F, WANG J J, GAN L. J. Alloys Compd., 2017, 721: 492-500.
37. [37]
  ZHUO Kai, LI Dan, WANG Jun-He. Micronanoelectron. Technol., 2021, 58(2): 137-143, 176. 禚凯, 李丹, 王俊和. 微纳电子技术, 2021, 58(2): 137-143, 176.
38. [38]
  LU M X, DENG Y G, LUO Y. Anal. Chem., 2019, 91(1): 888-895.LU M X, DENG Y G, LUO Y. Anal. Chem., 2019, 91(1): 888-895.

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沈阳化工大学材料科学与工程学院沈阳 110142

聚多巴胺包覆的钙钛矿修饰电极用于电化学检测水中铜、汞和铅离子

通讯作者: 郭玉晶,E-mail:guoyj@sxu.edu.cn

English

Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

Corresponding author: GUO Yu-Jing, guoyj@sxu.edu.cn

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

聚多巴胺包覆的钙钛矿修饰电极用于电化学检测水中铜、汞和铅离子

通讯作者: 郭玉晶,E-mail:guoyj@sxu.edu.cn

English

Institute of Environmental Science, Shanxi University, Taiyuan 030006, China

Corresponding author: GUO Yu-Jing, guoyj@sxu.edu.cn

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