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双核铜(Ⅱ)配合物{[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2}(Phen=1,10-菲咯啉,Nap=1-萘甲酸, EtOH=乙醇)的合成、晶体结构及性质

朱小明 ,  冯泳兰 ,  张复兴 ,  庾江喜 ,  蒋伍玖 ,  欧亚平 ,  邝代治

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引用本文: 朱小明, 冯泳兰, 张复兴, 庾江喜, 蒋伍玖, 欧亚平, 邝代治. 双核铜(Ⅱ)配合物{[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2}(Phen=1,10-菲咯啉,Nap=1-萘甲酸, EtOH=乙醇)的合成、晶体结构及性质[J]. 应用化学, 2016, 33(8): 932-938. doi: 10.11944/j.issn.1000-0518.2016.08.150402 shu
Citation:  ZHU Xiaoming, FENG Yonglan, ZHANG Fuxing, YU Jiangxi, JIANG Wujiu, OU Yaping, KUANG Daizhi. Synthesis, Crystal Structure and Properties of Dinuclear Copper(Ⅱ) Complex {[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2} (Phen=1,10-Phenanthroline; Nap=1-Naphthoic Acid; EtOH=Ethyl Alcohol)[J]. Chinese Journal of Applied Chemistry, 2016, 33(8): 932-938. doi: 10.11944/j.issn.1000-0518.2016.08.150402 shu

双核铜(Ⅱ)配合物{[Cu(Phen)(Nap)2]2·(EtOH)2·(H2O)2}(Phen=1,10-菲咯啉,Nap=1-萘甲酸, EtOH=乙醇)的合成、晶体结构及性质

  • 1.

    衡阳师范学院化学与材料科学学院, 功能金属有机材料湖南省普通高等学校重点实验室 湖南 衡阳 421008

    • 通讯作者: 邝代治,教授; Tel:0734-8486695; Fax:0734-3456099; E-mail:hnkcq@qq.com; 研究方向:金属有机化学
  • 基金项目:

    湖南省自然科学基金（13JJ3112) 

    湖南省科技计划（2014NK3086,2014FJ3060) 

    功能金属有机材料湖南省普通高校重点实验室开放基金资助项目（13K105,14K014,13K01-05,GN14K01) 

    湖南省重点学科基金和湖南省高校科技创新团队支持计划，衡阳师范学院科学基金（12C45) 

    湖南省教育厅基金（15C0199,15C0200,14C0171,14C0168）资助项目 

摘要: 合成了一种新型的配合物{[Cu（Phen）（Nap）2]2·（EtOH）2·（H2O）2}（Phen=1,10-菲咯啉,Nap=1-萘甲酸,EtOH=乙醇）。通过元素分析、红外光谱、热重等测试技术对其进行了表征，同时用X射线单晶衍射确定了其晶体结构，其配合物为双核铜结构。利用循环伏安法和发射光谱研究了该配合物的电化学和发光性能；采用紫外光谱和荧光光谱法研究了配合物与小牛胸腺DNA（ct-DNA）的相互作用。结果表明，配合物为不可逆氧化还原过程，其荧光发射光谱为416 nm，与小牛胸腺DNA（ct-DNA）以沟面结合方式相互作用,配合物结合常数Kb1=4.68×103 L/mol。

English

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  • 收稿日期:  2015-11-16
  • 网络出版日期:  2016-01-25
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