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磁性荧光双功能复合纳米粒子Fe3O4@SiO2@ZrO2:Tb3+的合成和表征

苑森文 ,  赵朗 ,  李宏涛

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引用本文: 苑森文, 赵朗, 李宏涛. 磁性荧光双功能复合纳米粒子Fe3O4@SiO2@ZrO2:Tb3+的合成和表征[J]. 应用化学, 2016, 33(8): 968-976. doi: 10.11944/j.issn.1000-0518.2016.08.150396 shu
Citation:  YUAN Senwen, ZHAO Lang, LI Hongtao. Synthesis and Characterization of Magnetic and Fluorescent Bifunctional Fe3O4@SiO2@ZrO2：Tb3+ Spherical Nanocomposites[J]. Chinese Journal of Applied Chemistry, 2016, 33(8): 968-976. doi: 10.11944/j.issn.1000-0518.2016.08.150396 shu

磁性荧光双功能复合纳米粒子Fe3O4@SiO2@ZrO2:Tb3+的合成和表征

  • 1.

    a 长春工业大学化学与生命科学学院 长春 130022;

  • 2.

    b 中国科学院长春应用化学研究所，稀土资源与利用国家重点实验室 长春 130022

    • 通讯作者: 李宏涛,教授; Tel:0431-85716471; E-mail:lihongtao@mail.ccut.edu.cn; 研究方向:材料化学;赵朗,副研究员; Tel:0431-85262054; E-mail:zhaolang@ciac.ac.cn; 研究方向:磁性材料的合成及性能; 李宏涛,教授; Tel:0431-85716471; E-mail:lihongtao@mail.ccut.edu.cn; 研究方向:材料化学;赵朗,副研究员; Tel:0431-85262054; E-mail:zhaolang@ciac.ac.cn; 研究方向:磁性材料的合成及性能
  • 基金项目:

    国家自然科学基金项目(21201160)；黑龙江大学功能无机材料化学教育部重点实验室开放基金 (21201160)

摘要: 通过原位反应合成法成功合成了一种新型水溶性的磁性荧光复合纳米粒子Fe3O4@SiO2@ZrO2：Tb3+，并通过扫描电子显微镜(SEM)、X射线粉末衍射仪(XRD)、红外光谱仪(FT-IR)、磁性测试仪和荧光(PL)光谱对其形貌、尺寸、相组成、磁性和荧光性能进行了表征。结果表明，核(Fe3O4@SiO2)壳(ZrO2：Tb3+)结构组成的磁性荧光复合纳米粒子具有超顺磁性，其饱和磁化强度达到36 emu/g，并且在494 nm(5D4→7F6)、549 nm(5D4→7F5)、587 nm(5D4→7F4)和625 nm(5D4→7F3)处具有4个Tb3+特有的荧光发射光谱带峰值。磁性荧光双功能的复合纳米粒子在生物医学领域具有潜在的应用价值。

English

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  • 收稿日期:  2015-11-10
  • 网络出版日期:  2015-12-24
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