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2,2'-联吡啶-3,3',6,6'-四羧酸过渡金属配合物的合成、结构及性质

邴颖颖 ,  吴振廷 ,  胡明

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引用本文: 邴颖颖, 吴振廷, 胡明. 2,2'-联吡啶-3,3',6,6'-四羧酸过渡金属配合物的合成、结构及性质[J]. 无机化学学报, 2015, 31(10): 2059-2064. doi: 10.11862/CJIC.2015.264 shu
Citation:  BING Ying-Ying, WU Zhen-Ting, HU Ming. Syntheses, Crystal Structures and Properties of Three Transition Metal Coordination Compounds Based on 2,2'-Bipyridine-3,3',6,6'-tetracarboxylic Acid[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 2059-2064. doi: 10.11862/CJIC.2015.264 shu

2,2'-联吡啶-3,3',6,6'-四羧酸过渡金属配合物的合成、结构及性质

  • 1.

    内蒙古自治区稀土物理与化学重点实验室, 内蒙古大学化学化工学院, 呼和浩特 010021

    • 通讯作者: 胡明,E-mail:hm988@126.com
  • 基金项目:

    国家自然科学基金(No.21361017) (No.21361017)

    内蒙古自然科学基金(No.2012MS0214) (No.2012MS0214)

    内蒙古高等学校科学技术研究重点研究(No.NJZZ12012)资助项目。 (No.NJZZ12012)

摘要: 以2,2'-联吡啶-3,3',6,6'-四羧酸(H4bptc)为配体,通过水热合成的方法与过渡金属盐合成了3个配合物,其分子式分别为[Co2(H2bptc)2(H2O)4]·bpe·9H2O(1),[Ni2(H2bptc)2(H2O)4]·bpe·9H2O(2),[Ni2(H2bptc)2(H2O)4]·0.5bpp·7H2O(3)(bpe=1,2-二(4-吡啶基)乙烯,bpp=1,2-二(4-吡啶基)乙烷)。用红外光谱,X-射线单晶衍射对化合物的晶体结构进行了表征,并对这3个配合物的热稳定性进行了测试。化合物1~3为单核结构的配合物,它们均通过分子间氢键形成三维超分子结构。

English

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  • 收稿日期:  2015-03-18
  • 网络出版日期:  2015-07-09
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