注册 English

两个含2-(2-吡啶基)咪唑衍生物的铜(Ⅱ)配合物的合成、晶体结构及发光性质

范艳 ,  瞿志荣 ,  金晓飞 ,  郭艳红 ,  王作祥

downloadPDF
引用本文: 范艳, 瞿志荣, 金晓飞, 郭艳红, 王作祥. 两个含2-(2-吡啶基)咪唑衍生物的铜(Ⅱ)配合物的合成、晶体结构及发光性质[J]. 无机化学学报, 2015, 31(10): 2051-2058. doi: 10.11862/CJIC.2015.262 shu
Citation:  FAN Yan, QU Zhi-Rong, JIN Xiao-Fei, GUO Yan-Hong, WANG Zuo-Xiang. Syntheses, Crystal Structures and Luminescent Properties of Two Cu(Ⅱ) Complexes with 2-(2-Pyridyl)imidazole Derivatives[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 2051-2058. doi: 10.11862/CJIC.2015.262 shu

两个含2-(2-吡啶基)咪唑衍生物的铜(Ⅱ)配合物的合成、晶体结构及发光性质

  • 1.

    1 杭州师范大学有机硅实验室, 杭州 311121;

  • 2.

    2 东南大学化学化工学院, 南京 211189

    • 通讯作者: 瞿志荣,E-mail:quzr@hznu.edu.cn;王作祥,E-mail:wangzxwzx@aliyun.com; 瞿志荣,E-mail:quzr@hznu.edu.cn;王作祥,E-mail:wangzxwzx@aliyun.com
摘要: 通过自然挥发法,合成了2个配合物[Cu(DMPM)2(Bz)][Cu(DMPM)(Bz)3]·H2O(1)和[Cu(PMA)Cl2](2)(DMPM=4,5-二甲基-2-(2-吡啶基)咪唑,PMA=[2-(2-吡啶基)咪唑-1-基]乙酸乙酯,Bz=苯甲酸根),并对其荧光、热稳定性及电子自旋共振光谱进行了研究。结构分析结果表明化合物1属于三斜晶系,P1空间群;化合物2属于单斜晶系,P21/c空间群。化合物1通过氢键的作用形成了三维超分子框架,化合物2通过氢键作用形成了二维层状结构。

English

  • 

    1. [1] Carlucci L, Ciani G, Proserpio D M, et al. Angew. Chem., 1999,111:3700-3704[1] Carlucci L, Ciani G, Proserpio D M, et al. Angew. Chem., 1999,111:3700-3704

    2. [2] Singh H, Chawla A S, Kapoor V K, et al. Prog. Med. Chem., 1980,17:151-183[2] Singh H, Chawla A S, Kapoor V K, et al. Prog. Med. Chem., 1980,17:151-183

    3. [3] Ostrovskii V A, Pevzner M S, Kofmna T P, et al. Targets Heterocycl. Syst., 1999,3:467-526[3] Ostrovskii V A, Pevzner M S, Kofmna T P, et al. Targets Heterocycl. Syst., 1999,3:467-526

    4. [4] Janiak C. J. Chem. Soc., Chem. Commun., 1994,4:545-547[4] Janiak C. J. Chem. Soc., Chem. Commun., 1994,4:545-547

    5. [5] Steel P J. Coord. Chem. Rev., 1990,106:227-265[5] Steel P J. Coord. Chem. Rev., 1990,106:227-265

    6. [6] Martinez-Lillo J, Armentano D, Giovanni D M, et al. Polyhe-dron, 2008,27:1447-1454[6] Martinez-Lillo J, Armentano D, Giovanni D M, et al. Polyhe-dron, 2008,27:1447-1454

    7. [7] Atencio R, Biradha K, Hennigar T L, et al. Cryst. Eng., 1998, 1:203-217[7] Atencio R, Biradha K, Hennigar T L, et al. Cryst. Eng., 1998, 1:203-217

    8. [8] Blake A J, Champness N R, Hubberstey P, et al. Coord. Chem. Rev., 1999,183:117-138[8] Blake A J, Champness N R, Hubberstey P, et al. Coord. Chem. Rev., 1999,183:117-138

    9. [9] Batten S R, Hoskins B F, Robson P, et al. Chem. Eur. J., 2000,6:156-161[9] Batten S R, Hoskins B F, Robson P, et al. Chem. Eur. J., 2000,6:156-161

    10. [10] Beatty A M. CrystEngCommun, 2001,3:243-255[10] Beatty A M. CrystEngCommun, 2001,3:243-255

    11. [11] Takodoro M, Isobe K, Uekusa H, et al. Angew. Chem., Int. Ed., 1999,38:95-98[11] Takodoro M, Isobe K, Uekusa H, et al. Angew. Chem., Int. Ed., 1999,38:95-98

    12. [12] Öhrström L, Larsson K, Borg S, et al. Chem. Eur. J., 2001,7:4805-4810[12] Öhrström L, Larsson K, Borg S, et al. Chem. Eur. J., 2001,7:4805-4810

    13. [13] Cancela J, Garmendia M J G, Quirós M. Inorg. Chim. Acta, 2001,313:156-159[13] Cancela J, Garmendia M J G, Quirós M. Inorg. Chim. Acta, 2001,313:156-159

    14. [14] Atencio R, Chacón M, González T, et al. Dalton Trans., 2004, 4:505-513[14] Atencio R, Chacón M, González T, et al. Dalton Trans., 2004, 4:505-513

    15. [15] Carranza J, Sletten J, Lloret F, et al. Polyhedron, 2009,28:2249-2257[15] Carranza J, Sletten J, Lloret F, et al. Polyhedron, 2009,28:2249-2257

    16. [16] Zhu D X, Lan Y Q, Fu Y M, et al. Acta Crystallogr., 2006, E62:m3479-3480[16] Zhu D X, Lan Y Q, Fu Y M, et al. Acta Crystallogr., 2006, E62:m3479-3480

    17. [17] Leita B A, Moubaraki B, Murray K S, et al. Polyhedron, 2005,24:2165-2172[17] Leita B A, Moubaraki B, Murray K S, et al. Polyhedron, 2005,24:2165-2172

    18. [18] Carranza J, Julve M, Sletten J. Inorg. Chim. Acta, 2008,361:2499-2507[18] Carranza J, Julve M, Sletten J. Inorg. Chim. Acta, 2008,361:2499-2507

    19. [19] Yu X Y, Cai S H, Chen Z. J. Inorg. Biochem., 2005,99:1945-1951[19] Yu X Y, Cai S H, Chen Z. J. Inorg. Biochem., 2005,99:1945-1951

    20. [20] Gerber T I A, Hosten E, Mayer P, et al. J. Coord. Chem., 2006,59(3):243-253[20] Gerber T I A, Hosten E, Mayer P, et al. J. Coord. Chem., 2006,59(3):243-253

    21. [21] Mishra H, Mukherjee R. J. Organomet. Chem., 2006,691:3545-3555[21] Mishra H, Mukherjee R. J. Organomet. Chem., 2006,691:3545-3555

    22. [22] Martínez-Lillo J, Armentano D, Munno G De, et al. Dalton Trans., 2008,1:40-43[22] Martínez-Lillo J, Armentano D, Munno G De, et al. Dalton Trans., 2008,1:40-43

    23. [23] Cheng C H, Liao W H, Shih H H. US Patent, 8062767. 2011-11-22.[23] Cheng C H, Liao W H, Shih H H. US Patent, 8062767. 2011-11-22.

    24. [24] Sheldrick G M. SHELX-97, Programs for Crystal Structure Analysis (Release 97-2), University of Göttingen, Germany, 1998.[24] Sheldrick G M. SHELX-97, Programs for Crystal Structure Analysis (Release 97-2), University of Göttingen, Germany, 1998.

    25. [25] Botova I N, Mirochnik A G, Kuryavyi V G, et al. Russ. Chem. Bull., 1994,43:973-975[25] Botova I N, Mirochnik A G, Kuryavyi V G, et al. Russ. Chem. Bull., 1994,43:973-975

    26. [26] Sakhir M, Chingsubam P. Indian J. Chem., 2004,43A:556-562[26] Sakhir M, Chingsubam P. Indian J. Chem., 2004,43A:556-562

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  438
  • HTML全文浏览量:  41
文章相关
  • 收稿日期:  2015-02-25
  • 网络出版日期:  2015-08-04
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net