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钴(Ⅱ)、锰(Ⅱ)与4-吡啶甲醛缩4-氨基安替比林配合物的合成、晶体结构与磁性

庞海霞 ,  袁曦明 ,  王贤文 ,  何雄

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引用本文: 庞海霞, 袁曦明, 王贤文, 何雄. 钴(Ⅱ)、锰(Ⅱ)与4-吡啶甲醛缩4-氨基安替比林配合物的合成、晶体结构与磁性[J]. 无机化学学报, 2015, 31(10): 2008-2014. doi: 10.11862/CJIC.2015.243 shu
Citation:  PANG Hai-Xia, YUAN Xi-Ming, WANG Xian-Wen, HE Xiong. Syntheses, Crystal Structures and Magnetic Properties of Co(Ⅱ) and Mn(Ⅱ) Complexes with 4-(4-Pyridinemethyleneamino)-1,5-dimethyl-2-phenyl-1,2-dihydropyrazol-3-one[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 2008-2014. doi: 10.11862/CJIC.2015.243 shu

钴(Ⅱ)、锰(Ⅱ)与4-吡啶甲醛缩4-氨基安替比林配合物的合成、晶体结构与磁性

  • 1.

    1 中国地质大学材料与化学学院, 教育部纳米矿物材料及应用工程研究中心, 武汉 430074;

  • 2.

    2 湖北工业大学轻工学部, 武汉 430068

    • 通讯作者: 袁曦明,E-mail:xmyuan@foxmail.com
  • 基金项目:

    国家自然科学基金(No.51173039,51202064) (No.51173039,51202064)

    教育部纳米矿物材料及应用工程研究中心开放课题(No.CUGNGM201412)资助项目。 (No.CUGNGM201412)

摘要: 以希夫碱衍生物4-氨基安替比林缩吡啶-4-甲醛为配体(L),采用溶剂热合成法,成功合成了2个Schiff碱Co(Ⅱ)配合物[CoLCl2](1)、Mn(Ⅱ)配合物[MnLCl2](2),通过元素分析、红外光谱IR、XRD、TG和磁性分析等测试手段对2个配合物进行表征,并用X-射线单晶衍射测得Co(Ⅱ)、Mn(Ⅱ)配合物的晶体结构。单晶结构表明,配合物1的晶体属于单斜晶系,空间群为Cc;配合物2的晶体属于三斜晶系,空间群为P1。配合物1是以Co(Ⅱ)为中心的扭曲四面体构型,配合物2是以Mn(Ⅱ)为中心的扭曲八面体构型。

English

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  • 收稿日期:  2015-03-18
  • 网络出版日期:  2015-06-23
通讯作者: 陈斌, bchen63@163.com
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