基于半刚性四面体四齿配体构筑的Zn(Ⅱ)/Cd(Ⅱ)配位聚合物及其性质

引用本文: 唐文渊, 任世斌, 朱冬冬, 韩得满, 周馨慧. 基于半刚性四面体四齿配体构筑的Zn(Ⅱ)/Cd(Ⅱ)配位聚合物及其性质[J]. 无机化学学报, 2015, 31(10): 2073-2078. doi: 10.11862/CJIC.2015.229 shu

Citation: TANG Wen-Yuan, REN Shi-Bin, ZHU Dong-Dong, HAN De-Man, ZHOU Xin-Hui. Crystal Structures and Properties of Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on Semirigid Tetrahedral Quadridentate Ligand[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 2073-2078. doi: 10.11862/CJIC.2015.229 shu

基于半刚性四面体四齿配体构筑的Zn(Ⅱ)/Cd(Ⅱ)配位聚合物及其性质

唐文渊 ^1, ,
任世斌 ^{1,2,
,} ,
朱冬冬 ^1, ,
韩得满 ^1, ,
周馨慧 ^{3,
,}

1.
1 台州学院医药化工学院, 台州 317000;
2.
2 南京大学化学化工学院生命分析化学国家重点实验室, 南京 210093;
3.
3 南京邮电大学有机电子与信息显示国家重点实验室及先进材料研究所, 南京 210023

通讯作者: 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn; 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn

基金项目:
国家自然科学基金(No.21471110,21375092) (No.21471110,21375092)

浙江省自然科学基金(No.LY12B01006) (No.LY12B01006)

中国博士后基金(No.2013M531314) (No.2013M531314)

生命分析国家重点实验室开放课题(No.SKLACLS1206) (No.SKLACLS1206)

浙江省大学生创新计划项目(No.2014R428014) (No.2014R428014)

台州市科技局项目(No.131KY03) (No.131KY03)

浙江省科技厅公益分析测试项目(No.2015C37034)资助项目。 (No.2015C37034)

摘要: 在水热的条件下,利用四(4-吡啶氧甲基)甲烷(L₁)或四(3-吡啶氧甲基)甲烷(L₂)、1,4-萘二甲酸(1,4-NDC)和d¹⁰金属离子发生自组装反应合成了2个化合物{[Cd₂(L₁)(1,4-NDC)₂]·2H₂O}_n(1)和{[Zn₂(L₂)(1,4-NDC)₂]·DMF·3H₂O)}_n(2)。单晶结构表明化合物1是通过L₁配体与一维链[Cd(1,4-NDC)]_n相连构建而成的三维骨架化合物,而化合物2是一对螺旋链与另外的一维链相互垂直交联而形成二维网络结构。更为重要的是,通过引入2种不同空间位阻的配体,研究了辅助配体对金属有机配位聚合物结构多样性的影响。另外,它们的荧光性质也做了相应的探讨。

关键词:

羧酸配体;异构化;空间位阻;荧光

English

Crystal Structures and Properties of Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on Semirigid Tetrahedral Quadridentate Ligand

1.
1 School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou, Zhejiang 317000, China;
2.
2 State Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China;
3.
3 Key Laboratory for Organic Electronics & Information Displays(KLOEID)and Institute of Advanced Materials(IAM), Nanjing University of Posts & Telecommunications, Nanjing 210023, China

Corresponding author: 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn; 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn

Received Date: 13 April 2015
Fund Project:
国家自然科学基金(No.21471110,21375092)

浙江省自然科学基金(No.LY12B01006)

中国博士后基金(No.2013M531314)

生命分析国家重点实验室开放课题(No.SKLACLS1206)

浙江省大学生创新计划项目(No.2014R428014)

台州市科技局项目(No.131KY03)

浙江省科技厅公益分析测试项目(No.2015C37034)资助项目。

Abstract: Two complexes, {[Cd₂(L₁)(1,4-NDC)₂]·2H₂O}_n (1) and {[Zn₂(L₂)(1,4-NDC)₂]·DMF·3H₂O)}_n (2) (L₁=tetrakis(4-pyridyloxymethylene)methane, L₂=tetrakis(3-pyridyloxymethylene)methane, 1,4-NDC=naphthalene-1,4-dicarbox-ylic acid) are obtained by the self-assembly reaction of L₁ or L₂, 1,4-NDC, and d¹⁰ metal ions under solvothermal conditions. The X-ray analysis reveals that 1 is constructed from a 1D zigzag chain [Cd(1,4-NDC)]_n which is linked by L₁ ligand to yield a 3D framework. And yet in case of 2, one double helix is mutually interdigitated by another 1D chain into a 2D network. Above all, the effect of steric hindrance of the auxiliary linker on the structural diversity of CPs can be discussed in great detail by the introduction of two kinds of auxiliary linkers with different steric hindrance. Additionally, their luminescent properties are also observed. CCDC: 1019510, 1; 1019511, 2.

Key words:

carboxylate ligands;isomerization;steric hindrance;luminescence

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沈阳化工大学材料科学与工程学院沈阳 110142

基于半刚性四面体四齿配体构筑的Zn(Ⅱ)/Cd(Ⅱ)配位聚合物及其性质

通讯作者: 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn; 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn

English

Crystal Structures and Properties of Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on Semirigid Tetrahedral Quadridentate Ligand

Corresponding author: 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn; 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn

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基于半刚性四面体四齿配体构筑的Zn(Ⅱ)/Cd(Ⅱ)配位聚合物及其性质

通讯作者: 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn; 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn

English

Crystal Structures and Properties of Zn(Ⅱ)/Cd(Ⅱ) Coordination Polymers Based on Semirigid Tetrahedral Quadridentate Ligand

Corresponding author: 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn; 任世斌,E-mail:renshibin@tzc.edu.cn;周馨慧,E-mail:iamxhzhou@njupt.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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