注册 English

基于四甲基取代六元瓜环的四核稀土镝簇合物的慢磁弛豫

陈文建 ,  孔祥建 ,  龙腊生 ,  郑兰荪

downloadPDF
引用本文: 陈文建, 孔祥建, 龙腊生, 郑兰荪. 基于四甲基取代六元瓜环的四核稀土镝簇合物的慢磁弛豫[J]. 无机化学学报, 2015, 31(9): 1867-1874. doi: 10.11862/CJIC.2015.226 shu
Citation:  CHEN Wen-Jian, KONG Xiang-Jian, LONG La-Sheng, ZHENG Lan-Sun. Slow Magnetic Relaxation in Sandwich-Type Tetranuclear Dysprosium Complex with TMeQ[6] (TMeQ[6]=α, α, δ, δ-Tetramethylcucurbit[6]uril)[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(9): 1867-1874. doi: 10.11862/CJIC.2015.226 shu

基于四甲基取代六元瓜环的四核稀土镝簇合物的慢磁弛豫

  • 1.

    固体表面物理化学国家重点实验室, 厦门大学化学化工学院化学系, 厦门 361005

    • 通讯作者: 孔祥建,E-mail:xjkong@xmu.edu.cn;龙腊生,E-mail:lslong@xmu.edu.cn; 孔祥建,E-mail:xjkong@xmu.edu.cn;龙腊生,E-mail:lslong@xmu.edu.cn
  • 基金项目:

    国家自然科学基金(nos.21422106,21371144,21431005)资助项目。 (nos.21422106,21371144,21431005)

摘要: 报道了2个基于四甲基取代六元瓜环的三明治型四核稀土簇合物,[Ln4(μ3-OH)4(μ2-OH)2(H2O)4(NO3)2(TMeQ[6])2]·(NO3)4·26H2O(Ln=Dy,1;Ln=Tb, 2)。晶体结构分析显示2个簇合物包含2个四甲基取代瓜环夹心的四核稀土立方烷结构,[Ln4(μ3-OH)4]8+。磁性研究显示化合物1显示了慢磁弛豫行为。由于六元瓜环配体可以有效的传递能量给稀土铽离子,化合物2具有较好的发光性能。

English

  • 

    1. [1] Troiani F, Affronte M. Chem. Soc. Rev., 2011,40:3119-3129[1] Troiani F, Affronte M. Chem. Soc. Rev., 2011,40:3119-3129

    2. [2] Rogez G, Donnio B, Terazzi E, et al. Adv. Mater., 2009,21:4323-4333[2] Rogez G, Donnio B, Terazzi E, et al. Adv. Mater., 2009,21:4323-4333

    3. [3] (a) Sessoli R, Gatteschi D, Caneschi A, et al. Nature, 1993, 365:141-143[3] (a) Sessoli R, Gatteschi D, Caneschi A, et al. Nature, 1993, 365:141-143

    4. [4]

      (b) Benelli C, Gatteschi D. Chem. Rev., 2002,102:2369-2387(b) Benelli C, Gatteschi D. Chem. Rev., 2002,102:2369-2387

    5. [5]

      (c) Bagai R, Christou G. Chem. Soc. Rev., 2009,38:1011-1026(c) Bagai R, Christou G. Chem. Soc. Rev., 2009,38:1011-1026

    6. [6]

      (d) Kostakis G E, Akoab A M, Powell A K. Chem. Soc. Rev., 2010,39:2238-2271(d) Kostakis G E, Akoab A M, Powell A K. Chem. Soc. Rev., 2010,39:2238-2271

    7. [4] (a) Coronado E, Day P. Chem. Rev., 2004,104:5419-5448[4] (a) Coronado E, Day P. Chem. Rev., 2004,104:5419-5448

    8. [8]

      (b) Sanvito S. Chem. Soc. Rev., 2011,40:3336-3355(b) Sanvito S. Chem. Soc. Rev., 2011,40:3336-3355

    9. [5] Sokol J J, Hee A G, Long J R. J. Am. Chem. Soc., 2002, 124:7656-7657[5] Sokol J J, Hee A G, Long J R. J. Am. Chem. Soc., 2002, 124:7656-7657

    10. [6] Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993,115:1804-1816[6] Sessoli R, Tsai H L, Schake A R, et al. J. Am. Chem. Soc., 1993,115:1804-1816

    11. [7] Murrie M. Chem. Soc. Rev., 2010,39:1986-1995[7] Murrie M. Chem. Soc. Rev., 2010,39:1986-1995

    12. [8] (a) Woodruff D N, Winpenny R E P, Layfield R A. Chem. Rev., 2013,113:5110-5148[8] (a) Woodruff D N, Winpenny R E P, Layfield R A. Chem. Rev., 2013,113:5110-5148

    13. [13]

      (b) Hewitt I J. Tang J K, Madhu N T, et al. Angew. Chem. Int. Ed., 2010,49:6352-6356(b) Hewitt I J. Tang J K, Madhu N T, et al. Angew. Chem. Int. Ed., 2010,49:6352-6356

    14. [14]

      (c) Guo Y N, Xu G F, Gamez P, et al. J. Am. Chem. Soc., 2010,132:8538-8539(c) Guo Y N, Xu G F, Gamez P, et al. J. Am. Chem. Soc., 2010,132:8538-8539

    15. [9] Bi Y F, Wang X T, Liao W P, et al. Inorg. Chem., 2009,48:11743-11747[9] Bi Y F, Wang X T, Liao W P, et al. Inorg. Chem., 2009,48:11743-11747

    16. [10] (a) Abbas G, Lan Y H, Kostakis G E, et al. Inorg. Chem., 2010,49:8067-8072[10] (a) Abbas G, Lan Y H, Kostakis G E, et al. Inorg. Chem., 2010,49:8067-8072

    17. [17]

      (b) Lin P H, Burchell T J, Ungur L, et al. Angew. Chem. Int. Ed., 2009,48:9489-9492(b) Lin P H, Burchell T J, Ungur L, et al. Angew. Chem. Int. Ed., 2009,48:9489-9492

    18. [18]

      (c) Ke H S, Gamez P, Zhao L, et al. Inorg. Chem., 2010,49:7549-7557(c) Ke H S, Gamez P, Zhao L, et al. Inorg. Chem., 2010,49:7549-7557

    19. [19]

      (d) Tang J K, Hewitt I, Madhu N T, et al. Angew. Chem. Int. Ed., 2006,45:1729-1733(d) Tang J K, Hewitt I, Madhu N T, et al. Angew. Chem. Int. Ed., 2006,45:1729-1733

    20. [11] Kong X J, Wu Y L, Long L S, et al. J. Am. Chem. Soc., 2009,131:6918-6919[11] Kong X J, Wu Y L, Long L S, et al. J. Am. Chem. Soc., 2009,131:6918-6919

    21. [12] Wang R, Selby H D, Liu H, et al. Inorg. Chem., 2002,41:278-286[12] Wang R, Selby H D, Liu H, et al. Inorg. Chem., 2002,41:278-286

    22. [13] Deacon G B, Feng T, Hockless D C R, et al. Chem. Commun., 1997:341-342[13] Deacon G B, Feng T, Hockless D C R, et al. Chem. Commun., 1997:341-342

    23. [14] Peng J B, Kong X J, Zhang Q C, et al. J. Am. Chem. Soc., 2014,136:17938-17941[14] Peng J B, Kong X J, Zhang Q C, et al. J. Am. Chem. Soc., 2014,136:17938-17941

    24. [15] Bürgstein M R, Gamer M T, Roesky P W, et al. J. Am. Chem. Soc., 2004,126:5213-5218[15] Bürgstein M R, Gamer M T, Roesky P W, et al. J. Am. Chem. Soc., 2004,126:5213-5218

    25. [16] Liu C M, Zhang D Q, Hao X, et al. Cryst. Growth Des., 2012,12:2948-2954[16] Liu C M, Zhang D Q, Hao X, et al. Cryst. Growth Des., 2012,12:2948-2954

    26. [17] (a) Hewitt I J, Lan Y, Anson C E, et al. Chem. Commun., 2009:6765-6767[17] (a) Hewitt I J, Lan Y, Anson C E, et al. Chem. Commun., 2009:6765-6767

    27. [27]

      (b) Gao Y, Xu G F, Zhao L, et al. Inorg. Chem., 2010,48:11495-11497(b) Gao Y, Xu G F, Zhao L, et al. Inorg. Chem., 2010,48:11495-11497

    28. [28]

      (c) Habib F, Lin P O, Long J, et al. J. Am. Chem. Soc., 2011,133:8830-8833(c) Habib F, Lin P O, Long J, et al. J. Am. Chem. Soc., 2011,133:8830-8833

    29. [18] (a) Behrend R, Meyer E, Rusche F. Justus Liebigs Ann. Chem., 1905,339:1-37[18] (a) Behrend R, Meyer E, Rusche F. Justus Liebigs Ann. Chem., 1905,339:1-37

    30. [30]

      (b) Freeman W A, Mock W L, Shih N Y. J. Am. Chem. Soc., 1981,103:7367-7368(b) Freeman W A, Mock W L, Shih N Y. J. Am. Chem. Soc., 1981,103:7367-7368

    31. [31]

      (d) Day A I, Blanch R J, Arnold A, et al. Angew. Chem., Int. Ed., 2002,41:275-277(d) Day A I, Blanch R J, Arnold A, et al. Angew. Chem., Int. Ed., 2002,41:275-277

    32. [19] (a) Flinn A, Hough G C, Stoddart J F, et al. Angew. Chem. Int. Ed., 1992,31:1475-1477[19] (a) Flinn A, Hough G C, Stoddart J F, et al. Angew. Chem. Int. Ed., 1992,31:1475-1477

    33. [33]

      (b) Zhao J Z, Kim H J, Oh J, et al. Angew. Chem., Int. Ed., 2001,40:4233-4235(b) Zhao J Z, Kim H J, Oh J, et al. Angew. Chem., Int. Ed., 2001,40:4233-4235

    34. [34]

      (c) Jon S Y, Selvapalam N, Oh D H. et al. J. Am. Chem. Soc., 2003,125:10186-10187(c) Jon S Y, Selvapalam N, Oh D H. et al. J. Am. Chem. Soc., 2003,125:10186-10187

    35. [35]

      (d) Huang W H, Zavalij P Y, Isaacs L. Angew. Chem. Int. Ed., 2007,119:7569-7571(d) Huang W H, Zavalij P Y, Isaacs L. Angew. Chem. Int. Ed., 2007,119:7569-7571

    36. [36]

      (e) Zhao Y J, Xue S F, Zhu Q J, et al. Chin. Sci. Bull., 2004,49:1111-1116(e) Zhao Y J, Xue S F, Zhu Q J, et al. Chin. Sci. Bull., 2004,49:1111-1116

    37. [20] Chen W J, Yu D H, Xiao X, et al. Inorg. Chem., 2011,50:6956-6964[20] Chen W J, Yu D H, Xiao X, et al. Inorg. Chem., 2011,50:6956-6964

    38. [21] (a) Hernandez-Molina R, Sokolov M N, Sykes A G. Acc. Chem. Res., 2001,34:223-230[21] (a) Hernandez-Molina R, Sokolov M N, Sykes A G. Acc. Chem. Res., 2001,34:223-230

    39. [39]

      (b) Fedin V P. J. Coord. Chem., 2004,30:151-152(b) Fedin V P. J. Coord. Chem., 2004,30:151-152

    40. [40]

      (c) Hernandez-Molina R, Sokolov M N, Clausen M, et al. Inorg. Chem., 2006,45:10567-10575(c) Hernandez-Molina R, Sokolov M N, Clausen M, et al. Inorg. Chem., 2006,45:10567-10575

    41. [41]

      (d) Gushchin A L, Ooi B, Harris P, et al. Inorg. Chem., 2009,48:3832-3839(d) Gushchin A L, Ooi B, Harris P, et al. Inorg. Chem., 2009,48:3832-3839

    42. [22] (a) Lü J, Lin J X, Cao M N, et al. Coord. Chem. Rev., 2013, 257:1334-1357[22] (a) Lü J, Lin J X, Cao M N, et al. Coord. Chem. Rev., 2013, 257:1334-1357

    43. [43]

      (b) Ni X L, Xue S F, Tao Z. Coord. Chem. Rev., 2015,287:89-113(b) Ni X L, Xue S F, Tao Z. Coord. Chem. Rev., 2015,287:89-113

    44. [23] (a) Tripolskaya A A, Mainicheva E A, Mitkina T V, et al. Russ. J. Coord. Chem., 2005,31:768-774[23] (a) Tripolskaya A A, Mainicheva E A, Mitkina T V, et al. Russ. J. Coord. Chem., 2005,31:768-774

    45. [45]

      (b) Thuery P. Inorg. Chem., 2009,48:4497-4513(b) Thuery P. Inorg. Chem., 2009,48:4497-4513

    46. [46]

      (c) Thuery P. Inorg. Chem., 2010,49:9078-9085(c) Thuery P. Inorg. Chem., 2010,49:9078-9085

    47. [47]

      (d) Thuery P. Inorg. Chem., 2011,50:10558-10560(d) Thuery P. Inorg. Chem., 2011,50:10558-10560

    48. [48]

      (e) Kushwaha S, Rao S A, Sudhakar P P. Inorg. Chem., 2012,51:267-273(e) Kushwaha S, Rao S A, Sudhakar P P. Inorg. Chem., 2012,51:267-273

    49. [49]

      (f) Liang L L, Ni X L, Zhao Y, et al. Inorg. Chem., 2013, 52:1909-1915(g) Liang L L, Zhao Y, Tao Z, et al. CrystEngComm, 2013, 15:3943-3950(h) Liu J X, Hu Y F, Lin R L, et al. CrystEngComm, 2012, 14:6983-6989(f) Liang L L, Ni X L, Zhao Y, et al. Inorg. Chem., 2013, 52:1909-1915(g) Liang L L, Zhao Y, Tao Z, et al. CrystEngComm, 2013, 15:3943-3950(h) Liu J X, Hu Y F, Lin R L, et al. CrystEngComm, 2012, 14:6983-6989

    50. [24] (a) Gerasko O A, Mainicheva E A, Naumova M I, et al. Inorg. Chem., 2008,47:8869-8880[24] (a) Gerasko O A, Mainicheva E A, Naumova M I, et al. Inorg. Chem., 2008,47:8869-8880

    51. [51]

      (b) Gerasko O A, Mainicheva E A, Naumova M I, et al. Eur. J. Inorg. Chem., 2008,3:416-424(b) Gerasko O A, Mainicheva E A, Naumova M I, et al. Eur. J. Inorg. Chem., 2008,3:416-424

    52. [25] SHELXTL Program Package, Version 6.10, Bruker AXS, Inc., Madison, WI, 2000.[25] SHELXTL Program Package, Version 6.10, Bruker AXS, Inc., Madison, WI, 2000.

    53. [26] (a) Yan P F, Lin P H, Habib F. et al. Inorg. Chem., 2011, 50:7059-7065[26] (a) Yan P F, Lin P H, Habib F. et al. Inorg. Chem., 2011, 50:7059-7065

    54. [54]

      (b) Jami A K, Baskar V, Sanudo E C, et al. Inorg. Chem., 2013,52:2432-2438(b) Jami A K, Baskar V, Sanudo E C, et al. Inorg. Chem., 2013,52:2432-2438

    55. [27] Langley S K, Moubaraki B, Forsyth C M, et al. Dalton Trans., 2010,39:1705-1708[27] Langley S K, Moubaraki B, Forsyth C M, et al. Dalton Trans., 2010,39:1705-1708

    56. [28] Bartolomé J, Filoti G, Kuncser V, et al. Phys. Rev. B, 2009, 80:014430[28] Bartolomé J, Filoti G, Kuncser V, et al. Phys. Rev. B, 2009, 80:014430

    57. [29] (a) Wernsdorfer W, Bhaduri S, Boskovic C, et al. Phys. Rev. B, 2002,65:180403[29] (a) Wernsdorfer W, Bhaduri S, Boskovic C, et al. Phys. Rev. B, 2002,65:180403

    58. [58]

      (b) Wernsdorfer W, Chakov N E, Christou G, et al. Phys. Rev. Lett., 2005,95:037203(b) Wernsdorfer W, Chakov N E, Christou G, et al. Phys. Rev. Lett., 2005,95:037203

  • 加载中
WeChat 扫一扫看文章
计量
  • PDF下载量:  0
  • 文章访问数:  460
  • HTML全文浏览量:  35
文章相关
  • 收稿日期:  2015-06-01
  • 网络出版日期:  2015-07-07
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章

All Rights Reserved by the Chinese Chemical Society   中国化学会 版权所有 京ICP备05002797号

本系统由北京仁和汇智信息技术有限公司开发    技术支持: info@rhhz.net