焙烧温度对In<sub>2</sub>TiO<sub>5</sub>纳米带晶型结构及光催化性能的影响

引用本文: 张钦库, 姚秉华, 于艳, 鲁盼, 庞波, 熊敏. 焙烧温度对In₂TiO₅纳米带晶型结构及光催化性能的影响[J]. 无机化学学报, 2015, 31(10): 1953-1958. doi: 10.11862/CJIC.2015.175 shu

Citation: ZHANG Qin-Ku, YAO Bing-Hua, YU Yan, LU Pan, PANG Bo, XIONG Min. Effects of Calcination Temperature on Crystal Structure and Photocatalytic Activity of In₂TiO₅ Nanobelts[J]. Chinese Journal of Inorganic Chemistry, 2015, 31(10): 1953-1958. doi: 10.11862/CJIC.2015.175 shu

焙烧温度对In₂TiO₅纳米带晶型结构及光催化性能的影响

张钦库 ^1,2, ,
姚秉华 ^{1,3,
,} ,
于艳 ^3, ,
鲁盼 ^1, ,
庞波 ^1, ,
熊敏 ^1,

1.
1 西安理工大学应用化学系, 西安 710048;
2.
2 榆林学院建筑工程系, 榆林 719000;
3.
3 陕西省尾矿资源综合利用重点实验室(商洛学院), 商洛 726000

通讯作者: 姚秉华,E-mail:bhyao@xaut.edu.cn

基金项目:
国家自然科学基金(No.21276208) (No.21276208)

陕西省矿产资源综合利用重点实验室开放基金(No.2014SKY-WK003) (No.2014SKY-WK003)

陕西省教育厅专项基金(No.15JK1862) (No.15JK1862)

西安理工大学博士学位论文创新基金资助项目。

摘要: 以Ti(OC₄H₉)₄、In(NO₃)₃和聚乙烯吡咯烷酮(PVP-K30)为原料,采用静电纺丝技术制备了In₂TiO₅纳米带。利用X射线衍射(XRD)、扫描电子显微镜(SEM)、紫外-可见漫反射光谱(UV-Vis DRS)和N₂吸附-脱附等技术对不同焙烧温度处理得到的样品进行表征,详细研究了焙烧温度对In₂TiO₅纳米带晶粒尺寸、形貌、比表面积和孔径的影响。以20 mg·L^-1的氟喹诺酮类抗生素左氧氟沙星(LEV)为目标降解物,125 W高压汞灯为光源,评价了不同焙烧温度下In₂TiO₅纳米带的光催化活性。结果表明,焙烧温度对In₂TiO₅的形貌与光催化活性有明显影响。当焙烧温度为800℃时,制备的In₂TiO₅纳米带表面光滑,其宽度为(552±58) nm、厚度约为140 nm,光催化活性最强,光照60 min,LEV的降解率可以达到95%。

关键词:

In₂TiO₅纳米带;静电纺丝;焙烧温度;光催化;降解

English

Effects of Calcination Temperature on Crystal Structure and Photocatalytic Activity of In₂TiO₅ Nanobelts

ZHANG Qin-Ku ^1,2, ,
YAO Bing-Hua ^{1,3,
,} ,
YU Yan ^3, ,
LU Pan ^1, ,
PANG Bo ^1, ,
XIONG Min ^1,

1.
1 Department of Applied Chemistry, Xi'an University of Technology, Xi'an 710048, China;
2.
2 Department of Building Engineering, Yulin University, Yulin, Shaanxi 719000, China;
3.
3 Shaanxi Key Laboratory of Comprehensive Utilization of Tailings Resources(Shangluo University), Shangluo, Shaanxi 726000, China

Corresponding author: 姚秉华,E-mail:bhyao@xaut.edu.cn

Received Date: 12 January 2015
Fund Project:
国家自然科学基金(No.21276208)

陕西省矿产资源综合利用重点实验室开放基金(No.2014SKY-WK003)

陕西省教育厅专项基金(No.15JK1862)

西安理工大学博士学位论文创新基金资助项目。

Abstract: In₂TiO₅ nanobelts were fabricated by means of electrospinning using Ti(OC₄H₉)₄、In(NO₃)₃ and polyvinyl pyrrolidone(PVP-K30) as raw materials. The nanobelts calcined at different temperature were characterized by XRD, SEM, UV-Vis DRS and N₂ adsorption-desorption isotherms. The influences of the calcination temperatures on the crystallite size, morphology, BET specific surface area and pore size of In₂TiO₅ nanobelts was studied. The photocatalytic activity of the as-prepared In₂TiO₅ nanobelts was evaluated by the photocatalytic degradation of levofloxacin (LEV) of fluoroquinolone antibiotics under the irradiation of the high pressure mercury lamp (125 W). The results show the significant effect of calcination temperature on the morphology and photocatalytic activity of In₂TiO₅ nanobelts. When the calcination temperature is 800℃, the In₂TiO₅ nanobelts prepared exhibit the best photocatalytic activity with smooth surface, the width of (552±58) nm and thickness of 140 nm. The degradation rate of LEV can be up to 95% after 60 min of irradiation.

Key words:

In₂TiO₅ nanobelts;electrospinning;calcinations temperature;photocatalysis;degradation

1. [1] Pallavi Shah, Deu S. Bhange, Aparna S. Deshpande, et al. Mater. Chem. Phys., 2009,117(2/3):399-407[1] Pallavi Shah, Deu S. Bhange, Aparna S. Deshpande, et al. Mater. Chem. Phys., 2009,117(2/3):399-407
2. [2] Wang W D, Huang F Q, Liu C M, et al. Mater. Sci. Eng. B, 2007,139(1):74-80[2] Wang W D, Huang F Q, Liu C M, et al. Mater. Sci. Eng. B, 2007,139(1):74-80
3. [3] Lu J, Wang H H, Dong S J, et al. J. Alloys Compd., 2014, 617:869-876[3] Lu J, Wang H H, Dong S J, et al. J. Alloys Compd., 2014, 617:869-876
4. [4] Pan C, Ding R, Hu Y, et al. Physica E, 2013,54:138-143[4] Pan C, Ding R, Hu Y, et al. Physica E, 2013,54:138-143
5. [5] Wang X, Fan H Q, Ren P R. Catal. Commun., 2013,31:37-41[5] Wang X, Fan H Q, Ren P R. Catal. Commun., 2013,31:37-41
6. [6] Zhao F, Lu Q F, Liu S W, et al. Mater. Lett., 2015,139:19-21[6] Zhao F, Lu Q F, Liu S W, et al. Mater. Lett., 2015,139:19-21
7. [7] Pang L X, Wang X Y, Tang X D. Solid State Sci., 2015,39:29-33[7] Pang L X, Wang X Y, Tang X D. Solid State Sci., 2015,39:29-33
8. [8] Wu M H, Chen J, Wang C, et al. Electrochim. Acta, 2014, 132:533-537[8] Wu M H, Chen J, Wang C, et al. Electrochim. Acta, 2014, 132:533-537
9. [9] Zhao D D, Yu Y L, Long H J, et al. Appl. Surf. Sci., 2014, 315:247-251[9] Zhao D D, Yu Y L, Long H J, et al. Appl. Surf. Sci., 2014, 315:247-251
10. [10] Rao R C, Yang M, Ling Q, et al. Microporous Mesoporous Mater., 2013,169:81-87[10] Rao R C, Yang M, Ling Q, et al. Microporous Mesoporous Mater., 2013,169:81-87
11. [11] Li W Q, Ma S Y, Luo J, et al. Mater. Lett., 2014,132:338-341[11] Li W Q, Ma S Y, Luo J, et al. Mater. Lett., 2014,132:338-341
12. [12] Ding Y, Liu Y X, Parisi J, et al. Biosens. Bioelectrom., 2011,28(1):393-398[12] Ding Y, Liu Y X, Parisi J, et al. Biosens. Bioelectrom., 2011,28(1):393-398
13. [13] YU Chang-Juan(于长娟), WANG Jin-Xian(王进贤), YU Chang-Ying(于长英), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(11):2013-2017[13] YU Chang-Juan(于长娟), WANG Jin-Xian(王进贤), YU Chang-Ying(于长英), et al. Chinese J. Inorg. Chem.(无机化学学报), 2010,26(11):2013-2017
14. [14] SUN Xia(孙霞), DONG Xiang-Ting(董相廷), WANG Jin-Xian(王进贤), et al. Chem. J. Chinese Universities(高等学校化学学报), 2011,32(10):2262-2267[14] SUN Xia(孙霞), DONG Xiang-Ting(董相廷), WANG Jin-Xian(王进贤), et al. Chem. J. Chinese Universities(高等学校化学学报), 2011,32(10):2262-2267
15. [15] Fan H T, Zhang T, Xu X J, et al. Sens. Actuator, B:Chem., 2011,153(1):83-88[15] Fan H T, Zhang T, Xu X J, et al. Sens. Actuator, B:Chem., 2011,153(1):83-88
16. [16] HU Yu-Yan(胡煜艳), QIAN Qing-Hua(钱清华), LIU Chang (刘畅), et al. Chinese J. Nonferrous Metals(中国有色金属学报), 2007,17(10):1711-1717[16] HU Yu-Yan(胡煜艳), QIAN Qing-Hua(钱清华), LIU Chang (刘畅), et al. Chinese J. Nonferrous Metals(中国有色金属学报), 2007,17(10):1711-1717
17. [17] CHEN Jie(陈捷), LIU Yan(刘延), HUANG Lei(黄磊), et al. Chem. J. Chinese Universities(高等学校化学学报), 2008, 29(7):1406-1411[17] CHEN Jie(陈捷), LIU Yan(刘延), HUANG Lei(黄磊), et al. Chem. J. Chinese Universities(高等学校化学学报), 2008, 29(7):1406-1411
18. [18] Chen Q H, Liu H L, Xin Y J, et al. Chem. Eng. J., 2014, 241:145-154[18] Chen Q H, Liu H L, Xin Y J, et al. Chem. Eng. J., 2014, 241:145-154

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

焙烧温度对In₂TiO₅纳米带晶型结构及光催化性能的影响

通讯作者: 姚秉华,E-mail:bhyao@xaut.edu.cn

English

Effects of Calcination Temperature on Crystal Structure and Photocatalytic Activity of In₂TiO₅ Nanobelts

Corresponding author: 姚秉华,E-mail:bhyao@xaut.edu.cn

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焙烧温度对In2TiO5纳米带晶型结构及光催化性能的影响

通讯作者: 姚秉华,E-mail:bhyao@xaut.edu.cn

English

Effects of Calcination Temperature on Crystal Structure and Photocatalytic Activity of In2TiO5 Nanobelts

Corresponding author: 姚秉华,E-mail:bhyao@xaut.edu.cn

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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