Interactions between pyridinium and Nd<sup>3+</sup>

Citation: Yu-Hai Liu, Jia-Jia Shi, Dan-Qing Gao, Yun-Long Gao, Ran Guo, Xiao-Feng Ling, Shi-Fu Weng, Yi-Zhuang Xu, Isao Noda, Jin-Guang Wu. Interactions between pyridinium and Nd³⁺[J]. Chinese Chemical Letters, 2015, 26(2): 182-186. doi: 10.1016/j.cclet.2015.01.014 shu

Interactions between pyridinium and Nd³⁺

通讯作者: Yi-Zhuang Xu,

基金项目:
This project is financially supported by the National Natural Science Foundation of China (No. 51373003) (No. 51373003)

Beijing Natural Science Foundation (No. 2122059). (No. 2122059)

摘要: In this paper, 2D asynchronous spectra generated by using the DAOSD approach was utilized to probe interactions between Nd³⁺ and pyridinium dissolved in aqueous solution. A series of cross peaks in the resultant 2D asynchronous spectrum confirms the occurrence of intermolecular interaction between Nd³⁺ and pyridinium. However, no coordination occurs between Nd³⁺ and pyridinium. Interaction between p electron from aromatic system and f electron from lanthanide ions account for the appearance of cross peaks in2Dasynchronous spectra.Because of the interaction, theemissionspectrumof pyridiniumexhibits a significant change when neodymium perchlorate was introduced into the system.

关键词:

English

Interactions between pyridinium and Nd³⁺

1.
a College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China;
2.
b College of Chemistry and Materials, Hebei Normal University, Shijiazhuang 050016, China;
3.
c School of Postgraduate, Liaoning University of Traditional Chinese Medicine, Shenyang 11660, China;
4.
d The third school of Clinical Medicine of Peking University, Beijing, 100083, China;
e Ninhai Doubly Advanced Martial Co.
e Ninhai Doubly Advanced Martial Co., Ltd., Ninhai 315602, China;
6.
f Department of Materials Science and Engineering, University of Delaware, Newark, DE 19716, USA

Corresponding author: Yi-Zhuang Xu,

Received Date: 31 October 2014
Available Online: 21 January 2015
Fund Project:

Abstract: In this paper, 2D asynchronous spectra generated by using the DAOSD approach was utilized to probe interactions between Nd³⁺ and pyridinium dissolved in aqueous solution. A series of cross peaks in the resultant 2D asynchronous spectrum confirms the occurrence of intermolecular interaction between Nd³⁺ and pyridinium. However, no coordination occurs between Nd³⁺ and pyridinium. Interaction between p electron from aromatic system and f electron from lanthanide ions account for the appearance of cross peaks in2Dasynchronous spectra.Because of the interaction, theemissionspectrumof pyridiniumexhibits a significant change when neodymium perchlorate was introduced into the system.

Key words:

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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Interactions between pyridinium and Nd³⁺

通讯作者: Yi-Zhuang Xu,

English

Interactions between pyridinium and Nd³⁺

Corresponding author: Yi-Zhuang Xu,

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