An ionic 2D inorganic-organic hybrid of tris[((1H-tetrazol-5-yl)methyl)morpholine]dodecatungstophosphate(Ⅴ)pentahydrate:Synthesis X-ray crystal structure and spectroscopic characterizations

Mohsen Nikpour Hossein Eshtiagh-Hosseini Masoud Mirzaei Amir Aghaei Kaju Ya Guang Chen Soroush Zarinabadi

引用本文: Mohsen Nikpour,  Hossein Eshtiagh-Hosseini,  Masoud Mirzaei,  Amir Aghaei Kaju,  Ya Guang Chen,  Soroush Zarinabadi. An ionic 2D inorganic-organic hybrid of tris[((1H-tetrazol-5-yl)methyl)morpholine]dodecatungstophosphate(Ⅴ)pentahydrate:Synthesis X-ray crystal structure and spectroscopic characterizations[J]. Chinese Chemical Letters, 2010, 21(4): 501-505. doi: 10.1016/j.cclet.2009.11.024 shu
Citation:  Mohsen Nikpour,  Hossein Eshtiagh-Hosseini,  Masoud Mirzaei,  Amir Aghaei Kaju,  Ya Guang Chen,  Soroush Zarinabadi. An ionic 2D inorganic-organic hybrid of tris[((1H-tetrazol-5-yl)methyl)morpholine]dodecatungstophosphate(Ⅴ)pentahydrate:Synthesis X-ray crystal structure and spectroscopic characterizations[J]. Chinese Chemical Letters, 2010, 21(4): 501-505. doi: 10.1016/j.cclet.2009.11.024 shu

An ionic 2D inorganic-organic hybrid of tris[((1H-tetrazol-5-yl)methyl)morpholine]dodecatungstophosphate(Ⅴ)pentahydrate:Synthesis X-ray crystal structure and spectroscopic characterizations

  • 基金项目:

    The financial support of this research by Islamic Azad University, Ahvaz Branch, is gratefully acknowledged. We are grateful to Faculty of Chemistry, Northeast Normal University of China for determining the structural analysis by single-crystal X-ray diffraction method.

摘要: A unique ionic hybrid material[C6H12N5O]3[(PO4)W12O36]·5H2O has been synthesized from the reaction of((1H-tetrazole-5-yl)morphline and α-H3 [(PO4)W12O36]·21H2O.It has successfully been charactrized by elemental analysis.IR and 1HNMR spectroscopies,TGA and single-crystal X-ray diffraction method.Thetitle compound is constructed from the three [C6H12N5O]+cations and α-Keggin[(PO4)W12O36]3-polyoxoanion.The most remarkable structural feature of this hybrid can be described as two-dimensional inorganic infinite plane-like(2D/∞[(PO4)W12O36]3-)which forming via van der Waais interactions along the x axis.

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