引用本文:
Jia Di Huang, Xiang Ping Hu, Zhuo Zheng. Synthesis of novel chiral phosphine-triazine ligand derived from α-phenylethylamine for Pd-catalyzed asymmetricallylic alkylation[J]. Chinese Chemical Letters,
2008, 19(3): 261-263.
doi:
10.1016/j.cclet.2007.12.027
Citation: Jia Di Huang, Xiang Ping Hu, Zhuo Zheng. Synthesis of novel chiral phosphine-triazine ligand derived from α-phenylethylamine for Pd-catalyzed asymmetricallylic alkylation[J]. Chinese Chemical Letters, 2008, 19(3): 261-263. doi: 10.1016/j.cclet.2007.12.027
Citation: Jia Di Huang, Xiang Ping Hu, Zhuo Zheng. Synthesis of novel chiral phosphine-triazine ligand derived from α-phenylethylamine for Pd-catalyzed asymmetricallylic alkylation[J]. Chinese Chemical Letters, 2008, 19(3): 261-263. doi: 10.1016/j.cclet.2007.12.027
Synthesis of novel chiral phosphine-triazine ligand derived from α-phenylethylamine for Pd-catalyzed asymmetricallylic alkylation
摘要:
A novel chiral phosphine-triazine ligand was synthesized from chiral α-phenylethylamine through a three-step procedure. In a model reaction of Pd-catalyzed allylic alkylation of rac-1, 3-diphenylprop-2-en-1-yl pivalate with dimethyl malonate, good enantioselectivity (90% e.e.) was obtained by using this ligand.
English
Synthesis of novel chiral phosphine-triazine ligand derived from α-phenylethylamine for Pd-catalyzed asymmetricallylic alkylation
Abstract:
A novel chiral phosphine-triazine ligand was synthesized from chiral α-phenylethylamine through a three-step procedure. In a model reaction of Pd-catalyzed allylic alkylation of rac-1, 3-diphenylprop-2-en-1-yl pivalate with dimethyl malonate, good enantioselectivity (90% e.e.) was obtained by using this ligand.
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