引用本文:
Xue Song Chen, Shi Jun Da, Li Hong Yang, Bo Yan Xu, Zhi Xiang Xie, Ying Li. A new convenient asymmetric approach to herbarumin Ⅲ[J]. Chinese Chemical Letters,
2007, 18(3): 255-257.
doi:
10.1016/j.cclet.2007.01.035
Citation: Xue Song Chen, Shi Jun Da, Li Hong Yang, Bo Yan Xu, Zhi Xiang Xie, Ying Li. A new convenient asymmetric approach to herbarumin Ⅲ[J]. Chinese Chemical Letters, 2007, 18(3): 255-257. doi: 10.1016/j.cclet.2007.01.035
Citation: Xue Song Chen, Shi Jun Da, Li Hong Yang, Bo Yan Xu, Zhi Xiang Xie, Ying Li. A new convenient asymmetric approach to herbarumin Ⅲ[J]. Chinese Chemical Letters, 2007, 18(3): 255-257. doi: 10.1016/j.cclet.2007.01.035
A new convenient asymmetric approach to herbarumin Ⅲ
摘要:
The asymmetric total synthesis of herbarumin Ⅲ 3, a naturally occurred phytotoxin, along with 8-epi-herbarumin Ⅲ 22, was succeeded in 12 steps from n-butyraldehyde based on Brown's asymmetric allylation, taking modified Julia olefination and Yamaguchi's macro-lactonization as key steps.
English
A new convenient asymmetric approach to herbarumin Ⅲ
Abstract:
The asymmetric total synthesis of herbarumin Ⅲ 3, a naturally occurred phytotoxin, along with 8-epi-herbarumin Ⅲ 22, was succeeded in 12 steps from n-butyraldehyde based on Brown's asymmetric allylation, taking modified Julia olefination and Yamaguchi's macro-lactonization as key steps.
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