引用本文:
Yan Fei Liu, Ke Long Huang, Dong Ming Peng, Su Qin Liu, Hong Wu. Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ε-caprolactone[J]. Chinese Chemical Letters,
2007, 18(2): 209-212.
doi:
10.1016/j.cclet.2006.12.002
Citation: Yan Fei Liu, Ke Long Huang, Dong Ming Peng, Su Qin Liu, Hong Wu. Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ε-caprolactone[J]. Chinese Chemical Letters, 2007, 18(2): 209-212. doi: 10.1016/j.cclet.2006.12.002
Citation: Yan Fei Liu, Ke Long Huang, Dong Ming Peng, Su Qin Liu, Hong Wu. Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ε-caprolactone[J]. Chinese Chemical Letters, 2007, 18(2): 209-212. doi: 10.1016/j.cclet.2006.12.002
Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ε-caprolactone
摘要:
A new degradable aliphatic poly(butylene-co-ε-caprolactone carbonate) (PBCL) was synthesized through the terpolymerization of carbon dioxide, 1,2-butylene oxide (BO) and ε-caprolactone (CL), a polymer supported bimetallic complex (PBM) was used as a catalyst. The terpolymers prepared were characterized by FT-IR, 1H NMR, 13C NMR, WXRD and DSC. The hydrolysis tests were carried out to appraise the degradability of the copolymers.
English
Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ε-caprolactone
Abstract:
A new degradable aliphatic poly(butylene-co-ε-caprolactone carbonate) (PBCL) was synthesized through the terpolymerization of carbon dioxide, 1,2-butylene oxide (BO) and ε-caprolactone (CL), a polymer supported bimetallic complex (PBM) was used as a catalyst. The terpolymers prepared were characterized by FT-IR, 1H NMR, 13C NMR, WXRD and DSC. The hydrolysis tests were carried out to appraise the degradability of the copolymers.
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Key words:
- Terpolymerization
- / Aliphatic polycarbonate
- / Degradability
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