高效光解水光电极设计的研究进展

引用本文: Zhiliang Wang, Lianzhou Wang. 高效光解水光电极设计的研究进展[J]. 催化学报, 2018, 39(3): 369-378. doi: 10.1016/S1872-2067(17)62998-X shu

Citation: Zhiliang Wang, Lianzhou Wang. Progress in designing effective photoelectrodes for solar water splitting[J]. Chinese Journal of Catalysis, 2018, 39(3): 369-378. doi: 10.1016/S1872-2067(17)62998-X shu

高效光解水光电极设计的研究进展

昆士兰大学化学工程学院与生物工程纳米技术澳大利亚研究所, 纳米材料中心, 圣露西亚, 昆士兰4072, 澳大利亚
基金项目:
澳大利亚研究理事会发现（DP）和未来奖学金（FF）计划

摘要: 光电化学（PEC）分解水过程被认为是由太阳能制氢的一个有前景的路径，PEC的关键在于高效电极的设计.最近的十多年里有关材料设计、共催化剂研究和电极制造取得了重大进展，但仍存在一些关键挑战尚未解决，包括迫切所需的转化效率.作为PEC过程的三个关键步骤：光采集、电荷转移和表面反应，发生在很广的时间尺度（10^-12-10⁰ s）内，如何组织好这一连串的步骤以促进各步骤间的无缝协作从而实现高效的PEC过程显得非常重要.基于高效稳定PEC光电极设计的研究进展，本文重点综述了整体考虑的三个主要标准，总结了一些基本原则和潜在的策略，尤其讨论了挑战与前景.

关键词:

English

Progress in designing effective photoelectrodes for solar water splitting

Nanomaterials Centre, School of Chemical Engineering and Australian Institute for Bioengineering and Nanotechnology, University of Queensland, St Lucia, QLD 4072, Australia
Received Date: 30 September 2017
Revised Date: 13 December 2017
Fund Project:
This work was supported by the Australian Research Council through its Discovery Project (DP) and Future Fellowship (FF) Program.

Abstract: Photoelectrochemical (PEC) water splitting process is regarded as a promising route to generate hydrogen by solar energy and at the heart of PEC is efficient electrode design. Great progress has been achieved in the aspects of material design, cocatalyst study, and electrode fabrication over the past decades. However, some key challenges remain unsolved, including the most demanded conversion efficiency issue. As three critical steps, i.e. light harvesting, charge transfer and surface reaction of the PEC process, occur in a huge range of time scale (from 10^-12 s to 10⁰ s), how to manage these subsequent steps to facilitate the seamless cooperation between each step to realize efficient PEC process is essentially important. This review focuses on an integral consideration of the three key criteria based on the recent progress on high efficient and stable photoelectrode design in PEC. The basic principles and potential strategies are summarized. Moreover, the challenge and perspective are also discussed.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

高效光解水光电极设计的研究进展

English

Progress in designing effective photoelectrodes for solar water splitting

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

高效光解水光电极设计的研究进展

English

Progress in designing effective photoelectrodes for solar water splitting

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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