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氢键的协同作用驱动水中苯甲醛的合成

杨祖金 ,  纪红兵

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引用本文: 杨祖金, 纪红兵. 氢键的协同作用驱动水中苯甲醛的合成[J]. 催化学报, 2014, 35(4): 590-598. doi: 10.1016/S1872-2067(14)60056-5 shu
Citation:  Zujin Yang, Hongbing Ji. Synergistic effect of hydrogen bonding mediated selective synthesis of benzaldehyde in water[J]. Chinese Journal of Catalysis, 2014, 35(4): 590-598. doi: 10.1016/S1872-2067(14)60056-5 shu

氢键的协同作用驱动水中苯甲醛的合成

    通讯作者: 纪红兵
  • 基金项目:

    国家自然科学基金(21376279, 21176268, 21036009) (21376279, 21176268, 21036009)

    广东省重大科技专项(2012A080103005) (2012A080103005)

    广东省部产学研结合项目(2011B090400439). (2011B090400439)

摘要: 以环氧氯丙烷作为交联溶剂合成和表征了纤维素功能化的β-环糊精, 考察了这种超分子聚合物作为一种多相催化剂用于苯甲醛的合成的催化性能. 结果表明, 该催化剂在温和的反应条件下具有较高的催化活性和选择性, 容易恢复和重新利用, 且活性没有大的损失. 进一步研究指出, β-环糊精聚合物中的b-环糊精能通过非极性共价键与肉桂醛形成主客包结物, 此外, β-环糊精和纤维素的功能基团能与肉桂醛通过O-H…O的氢键形成多重氢键的相互作用, 这种氢键的协同作用明显提高了催化剂的性能.

English

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  • 发布日期:  2014-04-20
  • 收稿日期:  2013-11-23
  • 网络出版日期:  2014-01-03
通讯作者: 陈斌, bchen63@163.com
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