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咪唑基介孔有机硅材料固载磷钼酸催化剂的制备及烯烃环氧化性能

王静 ,  邹永存 ,  孙渝 ,  Mximilin Hemgeserg ,  Dirk Shffner ,  高洪成 ,  宋晓静 ,  张文祥 ,  贾明君 ,  Werner R. Thiel

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引用本文: 王静, 邹永存, 孙渝, Mximilin Hemgeserg, Dirk Shffner, 高洪成, 宋晓静, 张文祥, 贾明君, Werner R. Thiel. 咪唑基介孔有机硅材料固载磷钼酸催化剂的制备及烯烃环氧化性能[J]. 催化学报, 2014, 35(4): 532-539. doi: 10.1016/S1872-2067(14)60025-5 shu
Citation:  Jing Wang, Yongcun Zou, Yu Sun, Maximilian Hemgesberg, Dirk Schaffner, Hongcheng Gao, Xiaojing Song, Wenxiang Zhang, Mingjun Jia, Werner R. Thiel. Electrostatic immobilization of phosphomolybdic acid on imidazolium-based mesoporous organosilicas for catalytic olefin epoxidation[J]. Chinese Journal of Catalysis, 2014, 35(4): 532-539. doi: 10.1016/S1872-2067(14)60025-5 shu

咪唑基介孔有机硅材料固载磷钼酸催化剂的制备及烯烃环氧化性能

    通讯作者: 贾明君, Werner R. Thiel; 贾明君, Werner R. Thiel
  • 基金项目:

    中国国家留学基金管理委员会 

    国家自然科学基金(21173100). (21173100)

摘要: 以含有咪唑阳离子的周期性介孔有机硅(PMO-ILs)材料为载体, 制备了一类固载化磷钼酸(PMA)多相催化材料(PMA@PMO-ILs), 并采用N2吸附-脱附实验、X射线衍射、原子吸收光谱、差热-热重分析、红外光谱、紫外光谱及固体核磁共振技术研究了材料的结构及物理化学性质. 结果表明, 磷钼酸通过静电相互作用被成功固载到PMO-ILs载体表面和孔道中, 且在制备过程中磷钼酸及载体基本结构均未发生变化. 反应结果表明, PMA@PMO-ILs材料在以叔丁基过氧化氢为氧化剂的环辛烯环氧化反应中表现出一定的催化活性和很高的选择性. 中断实验结果表明, 催化剂的主要活性中心在反应过程中未发生明显流失, 且催化剂经多次循环使用后活性及选择性基本保持不变. PMO-ILs中大量的咪唑阳离子能有效稳定磷钼酸阴离子, 使该催化材料表现出良好的稳定性.

English

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  • 发布日期:  2014-04-20
  • 收稿日期:  2013-11-14
  • 网络出版日期:  2014-01-02
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