引用本文:
刘国奇, 李国宝, 廖复辉, 林建华. [(n-C16H33)N(CH3)3]2[TiF6]·2H2O的合成、结构和热稳定性[J]. 物理化学学报,
2008, 24(11): 1945-1949.
doi:
10.1016/S1872-1508(08)60076-5
Citation: LIU Guo-Qi, LI Guo-Bao, LIAO Fu-Hui, LIN Jian-Hua. Synthesis, Structure and Thermal Property of [(n-C16H33)N(CH3)3]2[TiF6]·2H2O[J]. Acta Physico-Chimica Sinica, 2008, 24(11): 1945-1949. doi: 10.1016/S1872-1508(08)60076-5
Citation: LIU Guo-Qi, LI Guo-Bao, LIAO Fu-Hui, LIN Jian-Hua. Synthesis, Structure and Thermal Property of [(n-C16H33)N(CH3)3]2[TiF6]·2H2O[J]. Acta Physico-Chimica Sinica, 2008, 24(11): 1945-1949. doi: 10.1016/S1872-1508(08)60076-5
[(n-C16H33)N(CH3)3]2[TiF6]·2H2O的合成、结构和热稳定性
English
Synthesis, Structure and Thermal Property of [(n-C16H33)N(CH3)3]2[TiF6]·2H2O
Abstract:
A new compound dicetyltrimethylammonium hexafluorotitanium dihydrate, [(n-C16H33)N(CH3)3]2[TiF6]·2H2O (compound 1), was hydrothermally synthesized at 150 ℃ and characterized by single crystal X-ray diffraction, Fourier-transform infrared (FTIR) spectroscopy, elemental analysis, and thermogravimetric analysis. Compound 1 crystallizes in the monoclinic system, space group C2/c. It consists of hexafluorotitanium cations [TiF6]2-, water molecular (H2O), and cetyltrimethylammonium ions [(n-C16H33)N(CH3)3]+, which are connected together by extensive hydrogen bonding.
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Key words:
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Titaniumfluoride
- / Cetyltrimethylammonium
- / Hydrothermal reaction
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