Polymerizable Ionic Liquid Copolymer P(MMA-co-BVIm-Br) and Its Effect on the Surface Wettability of PVDF Blend Membranes

Citation: Chun-hui Du, Xu-min M, Chun-jin Wu, Mei-qiang Cai, Meng-xin Hub, Ting Wang. Polymerizable Ionic Liquid Copolymer P(MMA-co-BVIm-Br) and Its Effect on the Surface Wettability of PVDF Blend Membranes[J]. Chinese Journal of Polymer Science, 2015, 33(6): 857-868. doi: 10.1007/s10118-015-1634-y shu

Polymerizable Ionic Liquid Copolymer P(MMA-co-BVIm-Br) and Its Effect on the Surface Wettability of PVDF Blend Membranes

1.
School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310018, China
2.
Schoolof Food Science and Biotechnology, Zhejiang Gongshang University, Hangzhou 310018, China
基金项目:
This work was financially supported by the National Natural Science Foundation of China (Nos. 51103130 and 21004051) and Qianjiang Talents Project of Technology Office in Zhejiang Province (No. 2013R10070).

摘要: Polymerizable ionic liquid copolymer P(MMA-co-BVIm-Br) was synthesized by radical polymerization technique, and characterized by Fourier transform infrared spectrometry (FTIR), 1H Nuclear magnetic resonance (1H-NMR) and gel permeation chromatography (GPC). The resulting copolymer was used to prepare poly(vinylidene fluoride) (PVDF) blend membranes via a phase inversion method. The effects of the copolymer on the polymorphism, surface wettability and zeta potential () of the blend membranes were investigated by ATR-FTIR, contact angle instrument and zeta potential analyzer. Scanning electron microscopy (SEM and SEM-EDS) was also applied to investigate the morphology and the surface element changes of the fabricated membranes. The results indicated that P(MMA-co-BVIm-Br) copolymer existed on the surface of the membrane which made the blend membrane have a positive surface during the experimental pH range. The copolymer was also in favor of the formation of crystal phase in PVDF membranes. The contact angle experiment indicated that P(MMA-co-BVIm-Br) copolymer could switch the wettability of the blend membranes from hydrophilic to hydrophobic by exchanging Br- anion with PF6-. Compared with pure PVDF membranes, the water flux and water recovery flux of the blend membranes were enhanced obviously. The results from the flux recovery ratio (FR) and total fouling ratio (Rt) all suggested that the blend membranes had good anti-fouling properties.

关键词:

English

Polymerizable Ionic Liquid Copolymer P(MMA-co-BVIm-Br) and Its Effect on the Surface Wettability of PVDF Blend Membranes

1.
School of Environmental Science and Engineering, Zhejiang Gongshang University, Hangzhou 310018, China
2.
Schoolof Food Science and Biotechnology, Zhejiang Gongshang University, Hangzhou 310018, China
Received Date: 30 September 2014
Revised Date: 26 November 2014
Available Online: 05 June 2015
Fund Project:
This work was financially supported by the National Natural Science Foundation of China (Nos. 51103130 and 21004051) and Qianjiang Talents Project of Technology Office in Zhejiang Province (No. 2013R10070).

Abstract: Polymerizable ionic liquid copolymer P(MMA-co-BVIm-Br) was synthesized by radical polymerization technique, and characterized by Fourier transform infrared spectrometry (FTIR), 1H Nuclear magnetic resonance (1H-NMR) and gel permeation chromatography (GPC). The resulting copolymer was used to prepare poly(vinylidene fluoride) (PVDF) blend membranes via a phase inversion method. The effects of the copolymer on the polymorphism, surface wettability and zeta potential () of the blend membranes were investigated by ATR-FTIR, contact angle instrument and zeta potential analyzer. Scanning electron microscopy (SEM and SEM-EDS) was also applied to investigate the morphology and the surface element changes of the fabricated membranes. The results indicated that P(MMA-co-BVIm-Br) copolymer existed on the surface of the membrane which made the blend membrane have a positive surface during the experimental pH range. The copolymer was also in favor of the formation of crystal phase in PVDF membranes. The contact angle experiment indicated that P(MMA-co-BVIm-Br) copolymer could switch the wettability of the blend membranes from hydrophilic to hydrophobic by exchanging Br- anion with PF6-. Compared with pure PVDF membranes, the water flux and water recovery flux of the blend membranes were enhanced obviously. The results from the flux recovery ratio (FR) and total fouling ratio (Rt) all suggested that the blend membranes had good anti-fouling properties.

Key words:

1. [1]
  Vijayakrishna, K., Jewrajka, S.K., Ruiz, A., Marcilla, R., Pomposo, J.A., Mecerreyes, D., Taton, D. and Gnanou, Y., Macromolecules, 2008, 41: 6299
2. [2]
  Wasserscheid, P. and Keim, W., Angew. Chem.-Int. Ed., 2000, 39: 3772
3. [3]
  Ye, Y., Choi, J.H., Winey, K.I. and Elabd, Y.A.P., Macromolecules, 2012, 45: 7027
4. [4]
  Ye, Y. and Elabd, Y.A., Polymer, 2011, 52: 1309
5. [5]
  Mori, H., Yahagi, M. and Endo, T., Macromolecules, 2009, 42: 8082
6. [6]
  Genzer, J. and Efimenko, K., Science, 2000, 290: 213
7. [7]
  Chu, L.Y., Park, S.H., Yamaguchi, T. and Nakao, S., Langmuir, 2002, 18: 1856
8. [8]
  He, X.Y., Yang, W. and Pei, X.W., Macromolecules, 2008, 41: 4615
9. [9]
  Chi, Y.S., Lee, J.K., Lee, S. and Choi, I.S., Langmuir, 2004, 20: 3024
10. [10]
  Hidzir, N.M., Hill, David J.T., Martin, D. and Grndahl, L., Polymer, 2012, 53: 6063
11. [11]
  Zhu, J.Z., Zhu, L.P., Zhu, B.K. and Xu, Y.Y., J. Membr. Sci., 2011, 366: 176
12. [12]
  Du, C.H., Wu, C.J. and Wu, L.G., J. Appl. Polym. Sci., 2012, 124: E330
13. [13]
  Hester, J.F., Banerjee, P., Won, Y.Y., Akthakul, A., Acar, M.H. and Mayes, A.M., Macromolecules, 2002, 35: 7652
14. [14]
  Wang, W.Y. and Chen, L., J. Appl. Polym. Sci., 2007, 104: 1482
15. [15]
  Sasash, H., Bala, P.K., Yoshida, H. and Ito, E., Polymer, 1995, 36(25): 4805
16. [16]
  Lee, B.S., Chi, Y.S. and Lee, J.K., J. Am. Chem. Soc., 2004, 126: 480
17. [17]
  Zhang, P.Y., Xu, Z.L., Yang, H., Wei, Y.M. and Wu, W.Z., Chem. Eng. Sci., 2013, 97: 296
18. [18]
  Li, J.H., Shao, X.S., Zhou, Q., Li, M.Z. and Zhang, Q.Q., Appl. Surf. Sci., 2013, 265: 663
19. [19]
  Chi, W.S., Ahn, S.H., Jeon, H., Shul, Y.G. and Kim, J.H., J. Solid State Electr., 2012, 16: 3037
20. [20]
  Perchard, C. and Novak, A., Spectrochim. Acta A Mol., Biomol. Spectrosc., 1967, 23: 1953
21. [21]
  Bocaccio, T., Bottino, A., Capanelli, G. and Piaggio, P., J. Membr. Sci., 2002, 210: 315
22. [22]
  Uchida, E., Uyama, Y. and Ikada, Y., Langmuir, 1994, 10: 1193
23. [23]
  Zhu, C., Kang, E.T. and Neoh, K.G., Langmuir, 2005, 21(16): 7180
24. [24]
  Wittgren, B., Wahlund, K.G., Derand, H. and Wesslen, B., Macromolecules, 1996, 29(1): 268
25. [25]
  Inceoglu, S., Olugebefola, S.C., Acar, M.H. and Mayes, A.M., Des. Monomers Polym., 2004, 7(1~2): 181
26. [26]
  Hashim, N.A., Liu, F. and Li, K., J. Membr. Sci., 2009, 345: 134

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Polymerizable Ionic Liquid Copolymer P(MMA-co-BVIm-Br) and Its Effect on the Surface Wettability of PVDF Blend Membranes

English

Polymerizable Ionic Liquid Copolymer P(MMA-co-BVIm-Br) and Its Effect on the Surface Wettability of PVDF Blend Membranes

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中国化学会秘书处

Polymerizable Ionic Liquid Copolymer P(MMA-co-BVIm-Br) and Its Effect on the Surface Wettability of PVDF Blend Membranes

English

Polymerizable Ionic Liquid Copolymer P(MMA-co-BVIm-Br) and Its Effect on the Surface Wettability of PVDF Blend Membranes

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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通讯作者: 陈斌, bchen63@163.com

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