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Controlling structural topology of metal-organic frameworks with a desymmetric 4-connected ligand through the design of metal-containing nodes

Bin Wang ,  Hui Yang ,  Ya-Bo Xie ,  Yi-Bo Dou ,  Min-Jian Zhao ,  Jian-Rong Li

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引用本文: Bin Wang,  Hui Yang,  Ya-Bo Xie,  Yi-Bo Dou,  Min-Jian Zhao,  Jian-Rong Li. Controlling structural topology of metal-organic frameworks with a desymmetric 4-connected ligand through the design of metal-containing nodes[J]. Chinese Chemical Letters, 2016, 27(4): 502-506. shu
Citation:  Bin Wang,  Hui Yang,  Ya-Bo Xie,  Yi-Bo Dou,  Min-Jian Zhao,  Jian-Rong Li. Controlling structural topology of metal-organic frameworks with a desymmetric 4-connected ligand through the design of metal-containing nodes[J]. Chinese Chemical Letters, 2016, 27(4): 502-506. shu

Controlling structural topology of metal-organic frameworks with a desymmetric 4-connected ligand through the design of metal-containing nodes

  • Beijing Key Laboratory for Green Catalysis and Separation, Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China

  • 基金项目:

    This work was financially supported by the NSFC (Nos. 21322601, 21271015, 21406006, andU1407119) and Program for New Century Excellent Talents in University (No. NCET-13-0647).

摘要: Two new metal-organic frameworks (MOFs),[Cu2(H2O)2(BCPIA)] (BUT-20) and (Me2NH2)[In(BCPIA)] (BUT-21) were designed and synthesized through the solvothermal reaction between a newly created desymmetric 4-connected ligand, 5-(2, 6-bis(4-carboxyphenyl)pyridin-4-yl)isophthalic acid (H4BCPIA) and Cu(NO3)2·2.5H2O or In(NO3)3·5H2O, respectively, and characterized by single-crystal and powder Xray diffraction, thermogravimetric analysis, infrared spectroscopy, and elemental analysis. The two MOFs have three-dimensional structures, in which both the BCPIA4-ligand and metal-containing entities, Cu2(COO)4(H2O)2 and In(COO)4 act as 4-connected nodes. However, different linkage configurations of the two metal-containing nodes, quadrilateral Cu2(COO)4(H2O)2 and tetrahedral In(COO)4, lead to distinct structural networks of BUT-20 and -21, with Nbo and Unc topologies, respectively.

English

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  • 发布日期:  2016-01-25
  • 收稿日期:  2015-09-09
  • 修回日期:  2015-12-22
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