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A multi-responsive luminescent sensor towards Fe3+ and acetone based on a Cd-containing metal-organic framework

Ting Wang ,  Qing-Hui Liu ,  Ying Gao ,  Xiu-Yun Yang ,  Weiting Yang ,  Song Dang ,  Zhong-Ming Sun

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引用本文: Ting Wang,  Qing-Hui Liu,  Ying Gao,  Xiu-Yun Yang,  Weiting Yang,  Song Dang,  Zhong-Ming Sun. A multi-responsive luminescent sensor towards Fe3+ and acetone based on a Cd-containing metal-organic framework[J]. Chinese Chemical Letters, 2016, 27(4): 497-501. shu
Citation:  Ting Wang,  Qing-Hui Liu,  Ying Gao,  Xiu-Yun Yang,  Weiting Yang,  Song Dang,  Zhong-Ming Sun. A multi-responsive luminescent sensor towards Fe3+ and acetone based on a Cd-containing metal-organic framework[J]. Chinese Chemical Letters, 2016, 27(4): 497-501. shu

A multi-responsive luminescent sensor towards Fe3+ and acetone based on a Cd-containing metal-organic framework

  • a Changchun University of Science & Technology, School of Chemistry and Environmental Engineering, Changchun 130012, China;

  • b State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China;

  • c College of Physics, Jilin University, Changchun 130012, China

  • 基金项目:

    This work was supported by National Natural Science Foundation of China (Nos. 21171162, 21471144), Jilin Province Youth Foundation ([15TD$DIF]No. 20130522132JH), Jilin Province Natural Science Foundation ([15TD$DIF]No. 20150101181JC), Changchun Science and Technology Plan ([15TD$DIF]No. 2013059).

摘要: A Cd-containing metal-organic framework (CdL), formula as {[Cd3(L)2(H2O)6]·1.5DMF}, has been synthesized under solvothermal condition by the reaction of 4, 4', 4"-(methylsilanetriyl)tribenzoic acid (H3L) and Cd2+ ion. Single-crystal X-ray diffraction reveals that CdL displays a three-dimensional framework with 2-fold interpenetration and DMF molecules locate in the void space of the channels. A topological analysis of the framework indicates CdL is a 3, 4-connected pto net. The photoluminescence properties of CdL are systematically studied in detail. Impressively, CdL shows excellent detection performance towards Fe3+ ion and acetone in the sensing experiments, which undoubtedly demonstrates the great potential of CdL as a highly selective multi-responsive luminescent sensor for the detection of organic solvents and metal ions.

English

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  • 发布日期:  2016-01-14
  • 收稿日期:  2015-09-11
  • 修回日期:  2015-11-27
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