引用本文:
Chun JIN, Yin Juan JIA, Bin Bin FAN, Jing Hong MA, Rui Feng LI. Copper Tetrahydrosalen Complex Encapsulated in Zeolite Y:an Effective Heterogeneous Catalyst for the Oxidation of Cycloalkanes[J]. Chinese Chemical Letters,
2006, 17(3): 419-422.
Citation: Chun JIN, Yin Juan JIA, Bin Bin FAN, Jing Hong MA, Rui Feng LI. Copper Tetrahydrosalen Complex Encapsulated in Zeolite Y:an Effective Heterogeneous Catalyst for the Oxidation of Cycloalkanes[J]. Chinese Chemical Letters, 2006, 17(3): 419-422.
Citation: Chun JIN, Yin Juan JIA, Bin Bin FAN, Jing Hong MA, Rui Feng LI. Copper Tetrahydrosalen Complex Encapsulated in Zeolite Y:an Effective Heterogeneous Catalyst for the Oxidation of Cycloalkanes[J]. Chinese Chemical Letters, 2006, 17(3): 419-422.
Copper Tetrahydrosalen Complex Encapsulated in Zeolite Y:an Effective Heterogeneous Catalyst for the Oxidation of Cycloalkanes
摘要:
A new heterogeneous catalyst, copper tetrahydrosalen complex encapsulated in zeolite Y (denoted as Cu[H4]salen/Y) has been developed with flexible ligand method, and characterized by FTIR, DR UV-Vis spectroscopy, N2 adsorption/desorption at -196℃. This catalyst behaved like a bio-mimic enzyme, and exhibited much higher activity for the oxidation of cycloalkanes than Cusalen/Y prepared with the same method. The effects of the reaction conditions on the catalytic performance were investigated.
English
Copper Tetrahydrosalen Complex Encapsulated in Zeolite Y:an Effective Heterogeneous Catalyst for the Oxidation of Cycloalkanes
Abstract:
A new heterogeneous catalyst, copper tetrahydrosalen complex encapsulated in zeolite Y (denoted as Cu[H4]salen/Y) has been developed with flexible ligand method, and characterized by FTIR, DR UV-Vis spectroscopy, N2 adsorption/desorption at -196℃. This catalyst behaved like a bio-mimic enzyme, and exhibited much higher activity for the oxidation of cycloalkanes than Cusalen/Y prepared with the same method. The effects of the reaction conditions on the catalytic performance were investigated.
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Key words:
- Copper tetrahydrosalen complex
- / zeolite Y
- / encapsulation
- / cyclohexane oxidation
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