引用本文:
Kai LIU, Yong GUO, Jian XU, Shi Jun SHAO, Sheng Xiang JIANG. New Subsidiary Interaction Mode of Counteranions with the Periphery Cavity of Calix[4]pyrroles Binding with the Anion Subunits[J]. Chinese Chemical Letters,
2006, 17(3): 387-390.
Citation: Kai LIU, Yong GUO, Jian XU, Shi Jun SHAO, Sheng Xiang JIANG. New Subsidiary Interaction Mode of Counteranions with the Periphery Cavity of Calix[4]pyrroles Binding with the Anion Subunits[J]. Chinese Chemical Letters, 2006, 17(3): 387-390.
Citation: Kai LIU, Yong GUO, Jian XU, Shi Jun SHAO, Sheng Xiang JIANG. New Subsidiary Interaction Mode of Counteranions with the Periphery Cavity of Calix[4]pyrroles Binding with the Anion Subunits[J]. Chinese Chemical Letters, 2006, 17(3): 387-390.
New Subsidiary Interaction Mode of Counteranions with the Periphery Cavity of Calix[4]pyrroles Binding with the Anion Subunits
摘要:
The solution binding properties of calix[4]pyrroles with anion (as tetraalkylammonium salts) were investigated using UV-Vis spectroscopic techniques. The obvious red-shift of absorption maximum band of calix[4]pyrrole in EtOH in the presence of the tetramethylammonium (TMA+) salts or tetraethylammonium (TEA+) salts were observed, due to the charge-transfer interactions between the electron-rich pyrrole rings of calix[4]pyrroles and TMA+ or TEA+ cation subunit. The results indicated that calix[4]pyrrole receptors, which link the anionic species through multiple hydrogen bonding interactions, can use the periphery cavity for selectively binding cation subunits by cation-π charge-transfer interaction. The subsidiary interaction mode helps to further stabilize the calix[4]pyrrole-anion complex.
English
New Subsidiary Interaction Mode of Counteranions with the Periphery Cavity of Calix[4]pyrroles Binding with the Anion Subunits
Abstract:
The solution binding properties of calix[4]pyrroles with anion (as tetraalkylammonium salts) were investigated using UV-Vis spectroscopic techniques. The obvious red-shift of absorption maximum band of calix[4]pyrrole in EtOH in the presence of the tetramethylammonium (TMA+) salts or tetraethylammonium (TEA+) salts were observed, due to the charge-transfer interactions between the electron-rich pyrrole rings of calix[4]pyrroles and TMA+ or TEA+ cation subunit. The results indicated that calix[4]pyrrole receptors, which link the anionic species through multiple hydrogen bonding interactions, can use the periphery cavity for selectively binding cation subunits by cation-π charge-transfer interaction. The subsidiary interaction mode helps to further stabilize the calix[4]pyrrole-anion complex.
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