引用本文:
Xue Mei ZHAO, Xin Qi HAO, Bin LIU, Mao Ping SONG, Yang Jie WU. Synthesis and Structures of New Cyclopalladated Ferrocenylimines[J]. Chinese Chemical Letters,
2006, 17(3): 317-320.
Citation: Xue Mei ZHAO, Xin Qi HAO, Bin LIU, Mao Ping SONG, Yang Jie WU. Synthesis and Structures of New Cyclopalladated Ferrocenylimines[J]. Chinese Chemical Letters, 2006, 17(3): 317-320.
Citation: Xue Mei ZHAO, Xin Qi HAO, Bin LIU, Mao Ping SONG, Yang Jie WU. Synthesis and Structures of New Cyclopalladated Ferrocenylimines[J]. Chinese Chemical Letters, 2006, 17(3): 317-320.
Synthesis and Structures of New Cyclopalladated Ferrocenylimines
摘要:
The new complexes, [PdCl{C5H4FeC5H4CHRN=CHC4H3O}(Ph3P)] (R=H, CH3) were synthesized via two novel Schiff bases (C5H5FeC5H4CHRN=CHC4H3O, R=H, CH3) with lithium tetrachloropalladate (Ⅱ), and characterized by IR, elemental analysis, 1H NMR. Complex 5a was further determined by X-ray single crystal diffraction. We found that it contained an intramolecular N→Pd coordination in the compound Sa, and the palladium atom was bound to the unsubstituted Cp ring. The Pd-N, Pd-C (1) and Pd-O bond lengths were 2.121(3), 2.008(4) and 2.990(A), respectively.
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关键词:
- Heteroannular
- / ferrocenylimine
- / cyclopalladated
English
Synthesis and Structures of New Cyclopalladated Ferrocenylimines
Abstract:
The new complexes, [PdCl{C5H4FeC5H4CHRN=CHC4H3O}(Ph3P)] (R=H, CH3) were synthesized via two novel Schiff bases (C5H5FeC5H4CHRN=CHC4H3O, R=H, CH3) with lithium tetrachloropalladate (Ⅱ), and characterized by IR, elemental analysis, 1H NMR. Complex 5a was further determined by X-ray single crystal diffraction. We found that it contained an intramolecular N→Pd coordination in the compound Sa, and the palladium atom was bound to the unsubstituted Cp ring. The Pd-N, Pd-C (1) and Pd-O bond lengths were 2.121(3), 2.008(4) and 2.990(A), respectively.
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Key words:
- Heteroannular
- / ferrocenylimine
- / cyclopalladated
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