Studies on the Simultaneous Synthesis of Dimethyl Carbonate and Poly(ethylene terephthalate): Ⅰ. Catalytic Activity of Metal Acetate in Transesterification of Ethylene Carbonate with Dimethyl Terephthalate

Dan ZHANG Shu Yong JIA Yue WANG Jie YAO Yi ZENG Gong Ying WANG

引用本文: Dan ZHANG,  Shu Yong JIA,  Yue WANG,  Jie YAO,  Yi ZENG,  Gong Ying WANG. Studies on the Simultaneous Synthesis of Dimethyl Carbonate and Poly(ethylene terephthalate): Ⅰ. Catalytic Activity of Metal Acetate in Transesterification of Ethylene Carbonate with Dimethyl Terephthalate[J]. Chinese Chemical Letters, 2006, 17(12): 1607-1610. shu
Citation:  Dan ZHANG,  Shu Yong JIA,  Yue WANG,  Jie YAO,  Yi ZENG,  Gong Ying WANG. Studies on the Simultaneous Synthesis of Dimethyl Carbonate and Poly(ethylene terephthalate): Ⅰ. Catalytic Activity of Metal Acetate in Transesterification of Ethylene Carbonate with Dimethyl Terephthalate[J]. Chinese Chemical Letters, 2006, 17(12): 1607-1610. shu

Studies on the Simultaneous Synthesis of Dimethyl Carbonate and Poly(ethylene terephthalate): Ⅰ. Catalytic Activity of Metal Acetate in Transesterification of Ethylene Carbonate with Dimethyl Terephthalate

  • 基金项目:

    Gratitude is expressed to the National High Technology Research and Development Program of China (863Program) (No. 2003AA321010).

摘要: A novel direct method for preparation of dimethyl carbonate and poly(ethylene terephthalate) from ethylene carbonate and dimethyl terephthalate has been demonstrated in the presence of metal acetate catalysts, lithium acetate dihydrate showed highest catalytic activity with 47.9% yield of dimethyl carbonate. This method was a green chemical process.

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  • 收稿日期:  2006-09-01
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