A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units

Jing Lin CHEN Li Yi ZHANG Zhong Ning CHEN

引用本文: Jing Lin CHEN,  Li Yi ZHANG,  Zhong Ning CHEN. A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units[J]. Chinese Chemical Letters, 2005, 16(3): 372-374. shu
Citation:  Jing Lin CHEN,  Li Yi ZHANG,  Zhong Ning CHEN. A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units[J]. Chinese Chemical Letters, 2005, 16(3): 372-374. shu

A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units

  • 基金项目:

    This work was supported financially by the NNSF of China (No. 20171044, 20273074 and 20391001) and NSF of Fujian Province (E0310029).

摘要: A novel dimeric complex[Ru3Ⅲ,Ⅲ,Ⅱ(μ3-O)(μ-CH3COO) (CO)]2 (μ-dppf)(μ-odppf) (dppf=1, l'-bis(diphenylphosphio) ferrocene, odppf=1, 1'-bis(oxodiphenylphosphoranyl)ferrocene) (1) of oxo-centered triruthenium-aectate cluster units was synthesized and characterized by X-ray crystallography. Compound 1 exhibits a cyclic structure formed by linkages of two triruthenium cluster units Ru3Ⅲ,Ⅲ, Ⅱ (μ3-O)(μ-CH3COO)6(CO) through dppf and odppf ligands, respectively. The diameter of the molecular loop is ca. 1.0 nm.

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  • 收稿日期:  2004-01-12
通讯作者: 陈斌, bchen63@163.com
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