Asymmetric Intramolecular Cyclopropanation Induced by (β-Diketone)-copper Complex

Qing Fang CHENG Xing You XU Wei Xing MA Tian Pa YOU

引用本文: Qing Fang CHENG,  Xing You XU,  Wei Xing MA,  Tian Pa YOU. Asymmetric Intramolecular Cyclopropanation Induced by (β-Diketone)-copper Complex[J]. Chinese Chemical Letters, 2005, 16(3): 331-334. shu
Citation:  Qing Fang CHENG,  Xing You XU,  Wei Xing MA,  Tian Pa YOU. Asymmetric Intramolecular Cyclopropanation Induced by (β-Diketone)-copper Complex[J]. Chinese Chemical Letters, 2005, 16(3): 331-334. shu

Asymmetric Intramolecular Cyclopropanation Induced by (β-Diketone)-copper Complex

  • 基金项目:

    This work is supported by the National Natural Science Foundation of China and the Department of Education Excellent Teachers Foundation.

摘要: Asymmetric intramolecular cyclopropanation of allylic diazoacetate was investigated using a chiral (β-diketone)-copper complex as catalyst, excellent yield and enantioselectivity were achieved. Some factors influencing enantioselectivity were discussed.

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  • 收稿日期:  2004-03-08
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