引用本文:
Zheng Chang XIONG, Lu Ling WU, Xian HUANG. Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction[J]. Chinese Chemical Letters,
2004, 15(1): 35-36.
Citation: Zheng Chang XIONG, Lu Ling WU, Xian HUANG. Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction[J]. Chinese Chemical Letters, 2004, 15(1): 35-36.
Citation: Zheng Chang XIONG, Lu Ling WU, Xian HUANG. Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction[J]. Chinese Chemical Letters, 2004, 15(1): 35-36.
Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction
摘要:
The palladium catalyzed hydrostannation of 1-alkenylphosphonates gives the (E)-α-stannyl 1-alkenylphosphonates 2 stereospecifically. Compounds 2 can occur Stille coupling reaction to afford α, β-disubstituted vinylphosphonates with the retention of the configuration.
English
Stereospecifical Preparation of (E)-α-Stannyl-1-alkenylphosphonates and their Application in Stille Reaction
Abstract:
The palladium catalyzed hydrostannation of 1-alkenylphosphonates gives the (E)-α-stannyl 1-alkenylphosphonates 2 stereospecifically. Compounds 2 can occur Stille coupling reaction to afford α, β-disubstituted vinylphosphonates with the retention of the configuration.
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Key words:
- 1-Alkenylphosphonate
- / hydrostannation
- / Stille reaction
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