引用本文:
Xu Dong LIU, Meng Xian DING, Lian Xun GAO. Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers[J]. Chinese Chemical Letters,
2004, 15(1): 32-34.
Citation: Xu Dong LIU, Meng Xian DING, Lian Xun GAO. Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers[J]. Chinese Chemical Letters, 2004, 15(1): 32-34.
Citation: Xu Dong LIU, Meng Xian DING, Lian Xun GAO. Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers[J]. Chinese Chemical Letters, 2004, 15(1): 32-34.
Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers
摘要:
The synthesis of a new type of polymers with main chain chirality based on BINOL skeleton is described. Titanium-BINOLate catalysts are easily generated from these polymers and applied to the asymmetric reaction of Et2Zn with benzaldehyde. The products are obtained in good yields with moderate enantioselectivities.
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关键词:
- Asymmetric catalysis
- / chiral polymers
- / BINOL
English
Synthesis and Catalytic Application of Chiral 1, 1'-Binaphthyl Polymers
Abstract:
The synthesis of a new type of polymers with main chain chirality based on BINOL skeleton is described. Titanium-BINOLate catalysts are easily generated from these polymers and applied to the asymmetric reaction of Et2Zn with benzaldehyde. The products are obtained in good yields with moderate enantioselectivities.
-
Key words:
- Asymmetric catalysis
- / chiral polymers
- / BINOL
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