Atom Transfer Radical Polymerization of Methyl Methacrylate with α,α-Dichlorotoluene or α,α,α-Trichlorotoluene as Initiator

Zhi Feng FU Yan SHI Ming Zhi HUANG Shu Ke JIAO

引用本文: Zhi Feng FU,  Yan SHI,  Ming Zhi HUANG,  Shu Ke JIAO. Atom Transfer Radical Polymerization of Methyl Methacrylate with α,α-Dichlorotoluene or α,α,α-Trichlorotoluene as Initiator[J]. Chinese Chemical Letters, 1999, 10(7): 611-614. shu
Citation:  Zhi Feng FU,  Yan SHI,  Ming Zhi HUANG,  Shu Ke JIAO. Atom Transfer Radical Polymerization of Methyl Methacrylate with α,α-Dichlorotoluene or α,α,α-Trichlorotoluene as Initiator[J]. Chinese Chemical Letters, 1999, 10(7): 611-614. shu

Atom Transfer Radical Polymerization of Methyl Methacrylate with α,α-Dichlorotoluene or α,α,α-Trichlorotoluene as Initiator

摘要: The atom transfer radical polymerization (ATRP) of methyl methacrylate using α.α-dichlorotoluene or α.α,α-trichlorotoluene as the initiator and CuCl/2,2'-bipyridine complex as the catalyst was investigated. α,α-Dichlorotoluene gave good control of molecular weight with high initiation etliciency and low polydispersity. While α,α,α-trichlorotoluene gave very slow polymerization rate. which could be improved by the addition of Cu (0) to the system.

English

  • 加载中
计量
  • PDF下载量:  0
  • 文章访问数:  0
  • HTML全文浏览量:  0
文章相关
  • 收稿日期:  1998-12-07
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章