The Isomerization/Chlorination of O,O-D iallyl Thiophosphoric (-nic) Acid Esters with Phosphorus Oxychloride——A New Convenient Method for Synthesis of S-Alkyl Thiophosphoric(-nic) Acid Derivatives

Zheng Jie HE Ju Xiang LIU Zheng Hong ZHOU Chu Chi TANG

引用本文: Zheng Jie HE,  Ju Xiang LIU,  Zheng Hong ZHOU,  Chu Chi TANG. The Isomerization/Chlorination of O,O-D iallyl Thiophosphoric (-nic) Acid Esters with Phosphorus Oxychloride——A New Convenient Method for Synthesis of S-Alkyl Thiophosphoric(-nic) Acid Derivatives[J]. Chinese Chemical Letters, 1998, 9(10): 903-905. shu
Citation:  Zheng Jie HE,  Ju Xiang LIU,  Zheng Hong ZHOU,  Chu Chi TANG. The Isomerization/Chlorination of O,O-D iallyl Thiophosphoric (-nic) Acid Esters with Phosphorus Oxychloride——A New Convenient Method for Synthesis of S-Alkyl Thiophosphoric(-nic) Acid Derivatives[J]. Chinese Chemical Letters, 1998, 9(10): 903-905. shu

The Isomerization/Chlorination of O,O-D iallyl Thiophosphoric (-nic) Acid Esters with Phosphorus Oxychloride——A New Convenient Method for Synthesis of S-Alkyl Thiophosphoric(-nic) Acid Derivatives

  • 基金项目:

    This project was supported by National Natural Science Foundation of China and State Key laboratory of Elemento-Organic Chemistry.

摘要: The isomerization/chlorination of 0,0-diallyl thiophosphoric(-nic) acid esters with phosphrus oxychloride gives S-allyl thiophosphoro(-no)chloride, which reacts with substituted phenol in chloroform in the presence of triethylamine to afford eighteen new S-allyl thiophosphoric(-nic) acid derivatives. Thus, a new convenient method has been provided for synthesis of the title compounds.

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  • 收稿日期:  1997-08-25
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