引用本文:
Rui Lian SHAO, Wei Shi MIAO, Guang Fu YANG. Stereochemistry of Thionation Reaction of 1,3,2-Dioxaphosphorinan-2-ones with Lawessen's Reagent[J]. Chinese Chemical Letters,
1997, 8(4): 269-270.
Citation: Rui Lian SHAO, Wei Shi MIAO, Guang Fu YANG. Stereochemistry of Thionation Reaction of 1,3,2-Dioxaphosphorinan-2-ones with Lawessen's Reagent[J]. Chinese Chemical Letters, 1997, 8(4): 269-270.
Citation: Rui Lian SHAO, Wei Shi MIAO, Guang Fu YANG. Stereochemistry of Thionation Reaction of 1,3,2-Dioxaphosphorinan-2-ones with Lawessen's Reagent[J]. Chinese Chemical Letters, 1997, 8(4): 269-270.
Stereochemistry of Thionation Reaction of 1,3,2-Dioxaphosphorinan-2-ones with Lawessen's Reagent
摘要:
The stereochemistry of thionation reaction of 2-substituted-4-aryl-5,5-dimethyl-1.3.2-dioxaphosphorian-ones 1a-f with Lawessen's reagent (LR) was reported in this paper.The results indicated that the thionation reaction of LR proceeded predominantly with retention of configuration.The mechanism leading to retention was proposed by assuming a cyclic pentacoordinated intermidiate.
English
Stereochemistry of Thionation Reaction of 1,3,2-Dioxaphosphorinan-2-ones with Lawessen's Reagent
Abstract:
The stereochemistry of thionation reaction of 2-substituted-4-aryl-5,5-dimethyl-1.3.2-dioxaphosphorian-ones 1a-f with Lawessen's reagent (LR) was reported in this paper.The results indicated that the thionation reaction of LR proceeded predominantly with retention of configuration.The mechanism leading to retention was proposed by assuming a cyclic pentacoordinated intermidiate.
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