Citation:
QIU Kunyuan, YANG Yingfei, FENG Xinde. THE EFFECTS OF HINDERED AMINES ON METHYL METHACRYLATE POLYMERIZATION*[J]. Chinese Journal of Polymer Science,
1985, 3(4): 373-381.
THE EFFECTS OF HINDERED AMINES ON METHYL METHACRYLATE POLYMERIZATION*
摘要:
The effects of hindered amines, such as TMP, TMPM, TUV-770, on MMA and St homopoly-merization have been studied. It was found that in the MMA polymerization initiated with BPO orAIBN, the presence of TMPM, TUV-770 prolonged the induction period and a little change on Rp wasobserved. However, in the presence of TMP Rp increased slightly. The activation energy of poly-merization and polymerization rate equation were determined.
English
THE EFFECTS OF HINDERED AMINES ON METHYL METHACRYLATE POLYMERIZATION*
Abstract:
The effects of hindered amines, such as TMP, TMPM, TUV-770, on MMA and St homopoly-merization have been studied. It was found that in the MMA polymerization initiated with BPO orAIBN, the presence of TMPM, TUV-770 prolonged the induction period and a little change on Rp wasobserved. However, in the presence of TMP Rp increased slightly. The activation energy of poly-merization and polymerization rate equation were determined.
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