Citation:
ZHANG Yifeng, CAI Yiping, YANG Mujie, SHEN Zhiquan. THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*[J]. Chinese Journal of Polymer Science,
1985, 3(4): 367-372.
THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*
摘要:
This paper describes the polymerization of acetylene by coordination catalysts composed ofvarious neodymium compounds, (Nd (P204)3; Nd (P507)3; Nd (NO3)3 3P350; Nd (BA)3.2H2O; and Nd (acac)3.2H2O), aluminum trialkyl and an electron donor. The catalysts show fairly high catalyticactivity and high cis stereospecificity on acetylene polymerization at 30℃.
English
THE POLYMERIZATION OF ACETYLENE BY COORDINATION CATALYSTS COMPOSED OF NEODYMIUM COMPOUND, ALUMINUM TRIALKYL AND A THIRD COMPONENT*
Abstract:
This paper describes the polymerization of acetylene by coordination catalysts composed ofvarious neodymium compounds, (Nd (P204)3; Nd (P507)3; Nd (NO3)3 3P350; Nd (BA)3.2H2O; and Nd (acac)3.2H2O), aluminum trialkyl and an electron donor. The catalysts show fairly high catalyticactivity and high cis stereospecificity on acetylene polymerization at 30℃.
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