Synthesis of a Nine-atom Germanium Cluster K0.5[K(18-crown-6)]1.5Ge9·1.5en with Unprecedented "up" and "down" Chain Arrangement of Unit [-(Ge9-K-Ge9)3--]

Citation: WANG Yi, QIN Qian, SANG Rui-Li, XU Li. Synthesis of a Nine-atom Germanium Cluster K_0.5[K(18-crown-6)]_1.5Ge₉·1.5en with Unprecedented "up" and "down" Chain Arrangement of Unit [-(Ge₉-K-Ge₉)^3--][J]. Chinese Journal of Structural Chemistry, 2014, 33(7): 995-1000. shu

Synthesis of a Nine-atom Germanium Cluster K_0.5[K(18-crown-6)]_1.5Ge₉·1.5en with Unprecedented "up" and "down" Chain Arrangement of Unit [-(Ge₉-K-Ge₉)^3--]

a.
a. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
b.
b. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China
基金项目:
Supported by the National Natural Science Foundation of China (No. 21003125, 21073190) (No. 21003125, 21073190)

the Natural Science Foundation of Fujian Province (2010 J01057) (2010 J01057)

摘要: A new complex K_0.5[K(18-crown-6)]_1.5Ge₉·1.5en (1) which contains unprecedented "up" and "down" chain arrangement of unit [-(Ge₉-K-Ge₉)^3--] has been prepared by the reaction of K4Ge9 with HgS in ethylenediamine (en) in the presence of 18-crown-6(1,4,7,10,13,16-hexaoxacyclooctadecane), and characterized by X-ray structure analysis. The color of the title crystals (black), which is darker than that of the reported three compounds with chains of germanium clusters, may result from the naked K⁺ and their interactions with the chain. And the structure differences between 1 and the reported three compounds with chains of germanium have also been discussed.

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English

Synthesis of a Nine-atom Germanium Cluster K_0.5[K(18-crown-6)]_1.5Ge₉·1.5en with Unprecedented "up" and "down" Chain Arrangement of Unit [-(Ge₉-K-Ge₉)^3--]

a.
a. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China;
b.
b. Graduate School of the Chinese Academy of Sciences, Beijing 100039, China
Received Date: 24 December 2013
Fund Project:

Abstract: A new complex K_0.5[K(18-crown-6)]_1.5Ge₉·1.5en (1) which contains unprecedented "up" and "down" chain arrangement of unit [-(Ge₉-K-Ge₉)^3--] has been prepared by the reaction of K4Ge9 with HgS in ethylenediamine (en) in the presence of 18-crown-6(1,4,7,10,13,16-hexaoxacyclooctadecane), and characterized by X-ray structure analysis. The color of the title crystals (black), which is darker than that of the reported three compounds with chains of germanium clusters, may result from the naked K⁺ and their interactions with the chain. And the structure differences between 1 and the reported three compounds with chains of germanium have also been discussed.

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1.
沈阳化工大学材料科学与工程学院沈阳 110142

Synthesis of a Nine-atom Germanium Cluster K_0.5[K(18-crown-6)]_1.5Ge₉·1.5en with Unprecedented "up" and "down" Chain Arrangement of Unit [-(Ge₉-K-Ge₉)^3--]

English

Synthesis of a Nine-atom Germanium Cluster K_0.5[K(18-crown-6)]_1.5Ge₉·1.5en with Unprecedented "up" and "down" Chain Arrangement of Unit [-(Ge₉-K-Ge₉)^3--]

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