Citation:
QV Jing-Yan, MO Zong-Qiao, SUN Ya-Qiu. A Novel 3D Heterobimetallic Cyano-bridged Coordination Polymer {(NH4)2[Cd(H2O)Fe(CN)6]}n: Synthesis and Crystal Structure[J]. Chinese Journal of Structural Chemistry,
2014, 33(7): 990-994.
A Novel 3D Heterobimetallic Cyano-bridged Coordination Polymer {(NH4)2[Cd(H2O)Fe(CN)6]}n: Synthesis and Crystal Structure
摘要:
A novel heterobimetallic coordination polymer, {(NH4)2[Cd(H2O)Fe(CN)6]}n 1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group P21/n, a=7.4202(16), b=14.939(3), c=10.868(2) Å and β=91.660(3)°. For 1, five CN groups of Fe(CN)6]4- are involved in bridging. The polymer displays a 3D open microporous framework with 5-connected uninodal (46.64) topology.
English
A Novel 3D Heterobimetallic Cyano-bridged Coordination Polymer {(NH4)2[Cd(H2O)Fe(CN)6]}n: Synthesis and Crystal Structure
Abstract:
A novel heterobimetallic coordination polymer, {(NH4)2[Cd(H2O)Fe(CN)6]}n 1, has been synthesized by using the slow diffusion method and structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. The crystal crystallizes in the monoclinic system, space group P21/n, a=7.4202(16), b=14.939(3), c=10.868(2) Å and β=91.660(3)°. For 1, five CN groups of Fe(CN)6]4- are involved in bridging. The polymer displays a 3D open microporous framework with 5-connected uninodal (46.64) topology.
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