Citation:
XING Yuan-Yuan, CHEN Cong, SI Zhen-Jun, SHI Tao, DUAN Qian. Application of 4,4'-(2-Carboxypropane-1,3-diyl)dibenzoic Acid in Coordination Metal Complexes: Synthesis, Characterization, and Theoretical Studies[J]. Chinese Journal of Structural Chemistry,
2014, 33(7): 971-977.
Application of 4,4'-(2-Carboxypropane-1,3-diyl)dibenzoic Acid in Coordination Metal Complexes: Synthesis, Characterization, and Theoretical Studies
摘要:
[Pb(HL)(phen)]n (1) and [Cd3L2(phen)]n (2), where phen=1,10-phenanthroline and L=4,4'-(2-carboxylatopropane-1,3-diyl)dibenzoate, were hydrothermally prepared and fully characterized by X-ray single-crystal diffraction, infrared spectroscopy and thermogravimetric analyses. The decomposition temperature of 1 and 2 was measured to be ca. 304 and 416℃, respectively. The charge transfer transition based absorption of 1 and 2 was also verified by the powder scattering spectra and theoretical analyses.
English
Application of 4,4'-(2-Carboxypropane-1,3-diyl)dibenzoic Acid in Coordination Metal Complexes: Synthesis, Characterization, and Theoretical Studies
Abstract:
[Pb(HL)(phen)]n (1) and [Cd3L2(phen)]n (2), where phen=1,10-phenanthroline and L=4,4'-(2-carboxylatopropane-1,3-diyl)dibenzoate, were hydrothermally prepared and fully characterized by X-ray single-crystal diffraction, infrared spectroscopy and thermogravimetric analyses. The decomposition temperature of 1 and 2 was measured to be ca. 304 and 416℃, respectively. The charge transfer transition based absorption of 1 and 2 was also verified by the powder scattering spectra and theoretical analyses.
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Key words:
- metal organic complexes
- / synthesis
- / theoretical analyses
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