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油页岩的13C-NMR特征及FLASHCHAIN热解模拟研究

王擎 ,  任立国 ,  王锐 ,  柏静儒 ,  王浩添 ,  闫宇赫

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引用本文: 王擎, 任立国, 王锐, 柏静儒, 王浩添, 闫宇赫. 油页岩的13C-NMR特征及FLASHCHAIN热解模拟研究[J]. 燃料化学学报, 2014, 42(3): 303-308. shu
Citation:  WANG Qing, REN Li-guo, WANG Rui, BAI Jing-ru, WANG Hao-tian, YAN Yu-he. Characterization of oil shales by 13C-NMR and the simulation of pyrolysis by FLASHCHAIN[J]. Journal of Fuel Chemistry and Technology, 2014, 42(3): 303-308. shu

油页岩的13C-NMR特征及FLASHCHAIN热解模拟研究

    通讯作者: 王擎(1964-),男,博士,教授,E-mail:rlx888@126.com
  • 基金项目:

    国家自然科学基金(51276034)。 (51276034)

摘要: 采用固体 13C-NMR核磁共振技术表征了甘肃窑街矿区油页岩的碳骨架结构,分析并计算了油母质团簇化学结构参数,包括团簇平均碳原子数、芳碳原子数、脂碳原子数及芳环数。在热重红外分析仪(TG-FTIR)上进行了油页岩的热解实验,得到了热解产物的生成规律。结合样品的团簇化学结构参数,采用基于油页岩结构的FLASHCHAIN模型模拟其热解产物的生成过程;模拟结果与TG-FITR实验数据符合较好,印证了模型预测的合理性。

English

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  • 收稿日期:  2013-09-17
  • 网络出版日期:  2013-12-01
通讯作者: 陈斌, bchen63@163.com
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