{"extraData":"\"66312,17,13,19747,,\"","message":"成功","title":"成功","valid":"true"} SYNTHESIS,CRYSTAL STRUCTURE AND PROPERTIES OF TETRAETHYLAMMONIUM BIS [BIS(2-OXYPHENYL) DISULFIDE-O,O',S] MANGANESE

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Citation: Xue Tai CHEN, Han Qin LIU, Ling Hong WENG, Liang Ren HUANG, Da Xu WU, Xin Jian LEI, Bei Sheng KANG, Jia Xi LU. SYNTHESIS,CRYSTAL STRUCTURE AND PROPERTIES OF TETRAETHYLAMMONIUM BIS [BIS(2-OXYPHENYL) DISULFIDE-O,O',S] MANGANESE[J]. Chinese Chemical Letters, ;1990, 1(2): 123-124. shu

SYNTHESIS,CRYSTAL STRUCTURE AND PROPERTIES OF TETRAETHYLAMMONIUM BIS [BIS(2-OXYPHENYL) DISULFIDE-O,O',S] MANGANESE

Fujian Institute of Research on the Structure of Matter and Fuzhou Laboratory of Structural Chemistry, Chinese Academy of Sciences, Fuzhou 350002

The synthesis,crystal structure and properties of the first Mn(Ⅲ)-disulfide complex (Et₄N) [Mn(mp-mp)₂] were reported with the Mn(Ⅲ) ion in a S₂O₄ octahedron distorted due to Jahn-Teller effect.Spectroscopic data revealed its paramagnetic properties.
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