Citation: FENG Xue-Jiao, YANG Jun, NULI Yan-Na, WANG Jiu-Lin. Synthesis and Lithium Storage Performance of Porous Silicon/Carbon Composite Material from SiCl4[J]. Chinese Journal of Inorganic Chemistry, ;2013, 29(11): 2289-2296. doi: 10.3969/j.issn.1001-4861.2013.00.367
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Porous silicon/carbon composite was prepared via a mechanochemical reaction between Li13Si4 and SiCl4 under ball milling. Specific surface area of silicon/carbon composite can be adjusted by controlling the particle size distribution of Li13Si4. Effects of the carbon weight, specific surface area and active mass loading on the electrochemical performance were investigated. The results indicated that the composite material which combined specific surface area of 100.9 m2·g-1 and chemical vapor deposition method (CVD) carbon coating with 25.3wt% (ca.6 nm in thickness), exhibited a considerably high reversible capacity of 1900 mAh·g-1 and an excellent cycling stability with only 7.6% capacity decay after 50 cycles at a current density of 300 mA·g-1.
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